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Redox Reactions question

2022 · 25 Jun · Shift 2 · Q22
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Redox Reactions question

2022 · 25 Jun · Shift 2 · Q22

JEE MainChemistryRedox ReactionsNumerical+4 / −1
The neutralization occurs when 10 mL of 0.1M acid 'A' is allowed to react with 30 mL of 0.05 M base M(OH)2M(OH)_2M(OH)2​. The basicity of the acid 'A' is ‾\underline{\hspace{2cm}}​. [MMM is a metal]
Numerical answer
View written solutionFree

Correct answer: 3

  1. Write the neutralization relation

For complete neutralization:

equivalents of acid=equivalents of base\text{equivalents of acid} = \text{equivalents of base}equivalents of acid=equivalents of base

If acid AAA has basicity nnn, then 1 mole of acid gives nnn acidic H+H^+H+ ions.

Base is M(OH)2M(OH)_2M(OH)2​, so 1 mole of base gives 2 moles of OH−OH^-OH−. Hence its acidity factor is 2.


  1. Calculate moles of acid

Given:

  • Volume of acid =10 mL=0.010 L= 10\text{ mL} = 0.010\text{ L}=10 mL=0.010 L
  • Molarity of acid =0.1 M= 0.1\text{ M}=0.1 M

So, moles of acid:

nA=0.1×0.010=0.001n_A = 0.1 \times 0.010 = 0.001nA​=0.1×0.010=0.001

If its basicity is xxx, then acid equivalents are:

acid equivalents=0.001x\text{acid equivalents} = 0.001xacid equivalents=0.001x


  1. Calculate moles of base

Given:

  • Volume of base =30 mL=0.030 L= 30\text{ mL} = 0.030\text{ L}=30 mL=0.030 L
  • Molarity of base =0.05 M= 0.05\text{ M}=0.05 M

So, moles of base:

nB=0.05×0.030=0.0015n_B = 0.05 \times 0.030 = 0.0015nB​=0.05×0.030=0.0015

Each mole of M(OH)2M(OH)_2M(OH)2​ gives 2 equivalents of OH−OH^-OH−. Therefore base equivalents are:

base equivalents=0.0015×2=0.003\text{base equivalents} = 0.0015 \times 2 = 0.003base equivalents=0.0015×2=0.003


  1. Apply neutralization condition

0.001x=0.0030.001x = 0.0030.001x=0.003

x=0.0030.001=3x = \frac{0.003}{0.001} = 3x=0.0010.003​=3


  1. Final answer

The basicity of acid AAA is:

3\boxed{3}3​


  1. Comparison with stored answer

Stored correct answer = 3

Our derived answer = 3

So, the derived answer agrees with the stored answer.

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