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Redox Reactions question

2019 · 10 Jan · Shift 2 · Q22
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Redox Reactions question

2019 · 10 Jan · Shift 2 · Q22

JEE MainChemistryRedox ReactionsMCQ+4 / −1
In the reaction of oxalate with permanganate in acidic medium, the number of electrons involved in producing one molecule of CO2CO_2CO2​ is :
  1. A
    10
  2. B
    2
  3. C
    1
  4. D
    5
View written solutionFree

Correct answer: C

  1. Write the oxidation half-reaction for oxalate in acidic medium

Oxalate ion is \ceC2O42−\ce{C2O4^{2-}}\ceC2O42−. It gets oxidized to carbon dioxide:

\ceC2O42−−>2CO2+2e−\ce{C2O4^{2-} -> 2CO2 + 2e^-}\ceC2O42−−>2CO2+2e−

  1. Interpret the half-reaction

From the equation above:

  • 111 oxalate ion produces 222 molecules of \ceCO2\ce{CO2}\ceCO2
  • and in doing so, it loses 222 electrons.

So, electrons involved per molecule of \ceCO2\ce{CO2}\ceCO2 are:

2 e−2 molecules of CO2=1 e−\frac{2\ e^-}{2\ \text{molecules of } CO_2} = 1\ e^-2 molecules of CO2​2 e−​=1 e−

  1. Check via oxidation number

In \ceC2O42−\ce{C2O4^{2-}}\ceC2O42−, let oxidation state of each carbon be xxx:

2x+4(−2)=−22x + 4(-2) = -22x+4(−2)=−2 2x−8=−22x - 8 = -22x−8=−2 2x=6⇒x=+32x = 6 \Rightarrow x = +32x=6⇒x=+3

In \ceCO2\ce{CO2}\ceCO2, carbon is +4+4+4.

Thus each carbon goes from +3+3+3 to +4+4+4, meaning loss of:

1 e− per carbon atom1\ e^- \text{ per carbon atom}1 e− per carbon atom

Since one molecule of \ceCO2\ce{CO2}\ceCO2 contains one carbon atom, producing one molecule of \ceCO2\ce{CO2}\ceCO2 corresponds to 1 electron.

  1. Evaluate options
  • A: 101010 →\rightarrow→ incorrect
  • B: 222 →\rightarrow→ incorrect
  • C: 111 →\rightarrow→ correct
  • D: 555 →\rightarrow→ incorrect

Therefore, the correct answer is C.

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