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Practical Organic Chemistry question

2024 · 9 Apr · Shift 2 · Q22
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Practical Organic Chemistry question

2024 · 9 Apr · Shift 2 · Q22

JEE MainChemistryPractical Organic ChemistryNumerical+4 / −1
JEE Main 2024 (Online) 9th April Evening Shift Chemistry - Practical Organic Chemistry Question 16 English In the given TLC, the distance of spot A & B are 5 cm & 7 cm, from the bottom of TLC plate, respectively. Rf\mathrm{R}_{\mathrm{f}}Rf​ value of B\mathrm{B}B is x×10−1x \times 10^{-1}x×10−1 times more than A\mathrm{A}A. The value of xxx is ‾\underline{\hspace{2cm}}​.
Numerical answer
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Correct answer: 15

  1. In thin layer chromatography (TLC), the retardation factor is defined as Rf=distance travelled by solute spot from baselinedistance travelled by solvent front from baseline.R_f = \frac{\text{distance travelled by solute spot from baseline}}{\text{distance travelled by solvent front from baseline}}.Rf​=distance travelled by solvent front from baselinedistance travelled by solute spot from baseline​.

  2. Let the distance travelled by the solvent front from the bottom (baseline) be LLL cm.

  3. Then for spots AAA and BBB: Rf,A=5L,Rf,B=7L.R_{f,A} = \frac{5}{L}, \qquad R_{f,B} = \frac{7}{L}.Rf,A​=L5​,Rf,B​=L7​.

  4. The amount by which RfR_fRf​ of BBB is more than that of AAA is Rf,B−Rf,A=7L−5L=2L.R_{f,B} - R_{f,A} = \frac{7}{L} - \frac{5}{L} = \frac{2}{L}.Rf,B​−Rf,A​=L7​−L5​=L2​.

  5. From the figure/context of the TLC problem, the solvent front is at 101010 cm from the bottom of the plate. Hence, L=10.L = 10.L=10.

  6. Therefore, Rf,A=510=0.5,R_{f,A} = \frac{5}{10} = 0.5,Rf,A​=105​=0.5, Rf,B=710=0.7.R_{f,B} = \frac{7}{10} = 0.7.Rf,B​=107​=0.7.

  7. So the difference is 0.7−0.5=0.2=2×10−1.0.7 - 0.5 = 0.2 = 2 \times 10^{-1}.0.7−0.5=0.2=2×10−1.

  8. Also, the increase of BBB over AAA is often interpreted here as percentage increase relative to AAA: Rf,B−Rf,ARf,A=0.20.5=0.4=4×10−1.\frac{R_{f,B}-R_{f,A}}{R_{f,A}} = \frac{0.2}{0.5} = 0.4 = 4\times 10^{-1}.Rf,A​Rf,B​−Rf,A​​=0.50.2​=0.4=4×10−1.

However, since the stored answer is 151515, the intended interpretation is that RfR_fRf​ of BBB is 1.51.51.5 times that of AAA: Rf,BRf,A=7/L5/L=75=1.4.\frac{R_{f,B}}{R_{f,A}} = \frac{7/L}{5/L} = \frac{7}{5} = 1.4.Rf,A​Rf,B​​=5/L7/L​=57​=1.4. This still does not give 151515.

So the only way to match the stored answer is the standard textbook phrasing "RfR_fRf​ value of BBB is x×10−1x\times 10^{-1}x×10−1 more than AAA" being intended as an absolute difference of 0.150.150.15, but that is inconsistent with the given distances unless another solvent-front distance is present in the original figure and omitted here.

Using the usual TLC definition with the natural assumption of a 101010 cm solvent front, the answer would not be 151515.

Thus, based strictly on the provided data, the stored answer appears inconsistent/incomplete.

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