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Periodic Table and Periodicity question

2024 · 29 Jan · Shift 1 · Q2
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Periodic Table and Periodicity question

2024 · 29 Jan · Shift 1 · Q2

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Given below are two statements : one is labelled as Assertion A\mathbf{A}A and the other is labelled as Reason R\mathbf{R}R: Assertion A : The first ionisation enthalpy decreases across a period. Reason R\mathbf{R}R : The increasing nuclear charge outweighs the shielding across the period. In the light of the above statements, choose the most appropriate from the options given below :
  1. A
    A\mathbf{A}A is false but R\mathbf{R}R is true
  2. B
    Both A\mathbf{A}A and R\mathbf{R}R are true but R\mathbf{R}R is NOT the correct explanation of A\mathbf{A}A
  3. C
    Both A\mathbf{A}A and R\mathbf{R}R are true and R\mathbf{R}R is the correct explanation of A\mathbf{A}A
  4. D
    A\mathbf{A}A is true but R\mathbf{R}R is false
View written solutionFree

Correct answer: A

  1. Understand the assertion

    Assertion AAA: The first ionisation enthalpy decreases across a period.

    Across a period (from left to right), the general trend is that first ionisation enthalpy increases, not decreases.

    This is because:

    • nuclear charge increases,
    • electrons are added to the same shell,
    • shielding does not increase significantly,
    • hence effective nuclear charge increases,
    • electrons are held more strongly.

    Therefore, Assertion AAA is false.

  2. Understand the reason

    Reason RRR: The increasing nuclear charge outweighs the shielding across the period.

    This statement is true.

    Across a period:

    • the number of protons increases,
    • added electrons enter the same principal shell,
    • shielding effect increases only slightly,
    • so the net attraction on valence electrons increases.

    Hence, the increasing nuclear charge indeed outweighs shielding.

  3. Match with options

    • Assertion AAA = False
    • Reason RRR = True

    Therefore, the correct option is:

    A: A is false but R is true\boxed{\text{A: } A \text{ is false but } R \text{ is true}}A: A is false but R is true​

  4. Comparison with stored correct answer

    Stored correct answer = AAA

    Our derived answer also = AAA.

    So they agree.

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