JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Given below are two statements : one is labelled as Assertion and the other is labelled as Reason : Assertion A : The first ionisation enthalpy decreases across a period. Reason : The increasing nuclear charge outweighs the shielding across the period. In the light of the above statements, choose the most appropriate from the options given below :
- Ais false but is true
- BBoth and are true but is NOT the correct explanation of
- CBoth and are true and is the correct explanation of
- Dis true but is false
View written solutionFree
Correct answer: A
-
Understand the assertion
Assertion : The first ionisation enthalpy decreases across a period.
Across a period (from left to right), the general trend is that first ionisation enthalpy increases, not decreases.
This is because:
- nuclear charge increases,
- electrons are added to the same shell,
- shielding does not increase significantly,
- hence effective nuclear charge increases,
- electrons are held more strongly.
Therefore, Assertion is false.
-
Understand the reason
Reason : The increasing nuclear charge outweighs the shielding across the period.
This statement is true.
Across a period:
- the number of protons increases,
- added electrons enter the same principal shell,
- shielding effect increases only slightly,
- so the net attraction on valence electrons increases.
Hence, the increasing nuclear charge indeed outweighs shielding.
-
Match with options
- Assertion = False
- Reason = True
Therefore, the correct option is:
-
Comparison with stored correct answer
Stored correct answer =
Our derived answer also = .
So they agree.
More from Periodic Table and Periodicity
- Given below are two statements : Statement I : The electronegativity of group 14 elements from to , gradually decreases. Statement II : Group 14 contains non-metallic, metallic, as well as metalloid elements. In…2024 · MCQ
- Anomalous behavior of oxygen is due to its2024 · MCQ
- Given below are two statements: Statement I : Fluorine has most negative electron gain enthalpy in its group. Statement II : Oxygen has least negative electron gain enthalpy in its group. In the light of the above statements, choose the…2024 · MCQ
- The element having the highest first ionization enthalpy is2024 · MCQ
- Match List I with List II. Choose the correct answer from the options given below : Includes table2024 · MCQ
- If IUPAC name of an element is "Unununnium" then the element belongs to nth group of Periodic table. The value of n is .2024 · Numerical
- Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R: Assertion A: is more acidic than . Reason R: Bond dissociation enthalpy of …2024 · MCQ
- Given below are two statements: Statement - I: Along the period, the chemical reactivity of the elements gradually increases from group 1 to group 18 . Statement - II: The nature of oxides formed by group 1 elements is basic while that of…2024 · MCQ