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Periodic Table and Periodicity question

2019 · 8 Apr · Shift 1 · Q14
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Periodic Table and Periodicity question

2019 · 8 Apr · Shift 1 · Q14

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The lathanide ion that would show colour is :
  1. A
    Sm3+Sm^{3+}Sm3+
  2. B
    Gd3+Gd^{3+}Gd3+
  3. C
    Lu3+Lu^{3+}Lu3+
  4. D
    La3+La^{3+}La3+
View written solutionFree

Correct answer: A, B

  1. Reason for colour in lanthanide ions
    Lanthanide ions show colour due to fff-fff electronic transitions.
    These transitions are possible only when the ion has partially filled 4f4f4f orbitals.

  2. Check electronic configurations of the given ions

    • La3+La^{3+}La3+
      LaLaLa has atomic number 575757.
      Neutral configuration: [Xe]5d16s2[Xe]5d^16s^2[Xe]5d16s2
      La3+=[Xe]4f0La^{3+} = [Xe]4f^0La3+=[Xe]4f0 No 4f4f4f electron  no fff-fff transition  colourless.

    • Sm3+Sm^{3+}Sm3+
      SmSmSm has atomic number 626262.
      Neutral configuration: [Xe]4f66s2[Xe]4f^66s^2[Xe]4f66s2
      Sm3+=[Xe]4f5Sm^{3+} = [Xe]4f^5Sm3+=[Xe]4f5 Partially filled 4f4f4f subshell  fff-fff transitions possible  coloured.

    • Gd3+Gd^{3+}Gd3+
      GdGdGd has atomic number 646464.
      Neutral configuration: [Xe]4f75d16s2[Xe]4f^75d^16s^2[Xe]4f75d16s2
      Gd3+=[Xe]4f7Gd^{3+} = [Xe]4f^7Gd3+=[Xe]4f7 This is a half-filled 4f4f4f subshell. Although such ions are relatively less intensely coloured, they still have partially filled 4f4f4f orbitals and can show colour.

    • Lu3+Lu^{3+}Lu3+
      LuLuLu has atomic number 717171.
      Neutral configuration: [Xe]4f145d16s2[Xe]4f^{14}5d^16s^2[Xe]4f145d16s2
      Lu3+=[Xe]4f14Lu^{3+} = [Xe]4f^{14}Lu3+=[Xe]4f14 Completely filled 4f4f4f subshell  no fff-fff transition  colourless.

  3. Evaluate options

    • A: Sm3+Sm^{3+}Sm3+  coloured
    • B: Gd3+Gd^{3+}Gd3+  also coloured
    • C: Lu3+Lu^{3+}Lu3+  colourless
    • D: La3+La^{3+}La3+  colourless
  4. Conclusion
    The ions with partially filled 4f4f4f orbitals should show colour. Hence both Sm3+ and Gd3+Sm^{3+} \text{ and } Gd^{3+}Sm3+ and Gd3+ can show colour.

Since this is given as a single-correct MCQ, the stored answer AAA is incomplete. Option BBB should also qualify on the basis of standard lanthanide colour theory.

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