JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The first and second ionisation enthalpies of a metal are 496 and 4560 kJ mol–1, respectively. How many moles of and , respectively, will be needed to react completely with 1 mole of the metal hydroxide ?
- A1 and 2
- B1 and 0.5
- C1 and 1
- D2 and 0.5
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Correct answer: B
- Identify the metal from ionisation enthalpies
The given ionisation enthalpies are:
- First ionisation enthalpy
- Second ionisation enthalpy
There is a very large jump from the first to the second ionisation enthalpy. This means that after losing one electron, the metal attains a stable noble gas configuration.
So the metal is a Group 1 metal and forms a monovalent ion:
Hence, its hydroxide will be:
- Reaction with
The reaction is:
From the equation,
- mole of reacts with mole of
So for mole of metal hydroxide, required mole.
- Reaction with
Since is dibasic, the balanced reaction is:
From the equation,
- moles of react with mole of
Therefore, for mole of , required is:
- Final answer
Thus, the required moles of and , respectively, are:
So the correct option is B.
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