Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Periodic Table and Periodicity question

2020 · 9 Jan · Shift 2 · Q3
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Periodic Table and Periodicity
  5. /2020 · 9 Jan · Shift 2 · Q3

Periodic Table and Periodicity question

2020 · 9 Jan · Shift 2 · Q3

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The first and second ionisation enthalpies of a metal are 496 and 4560 kJ mol–1, respectively. How many moles of HClHClHCl and H2SO4H_2SO_4H2​SO4​, respectively, will be needed to react completely with 1 mole of the metal hydroxide ?
  1. A
    1 and 2
  2. B
    1 and 0.5
  3. C
    1 and 1
  4. D
    2 and 0.5
View written solutionFree

Correct answer: B

  1. Identify the metal from ionisation enthalpies

The given ionisation enthalpies are:

  • First ionisation enthalpy =496 kJ mol−1= 496\,\text{kJ mol}^{-1}=496kJ mol−1
  • Second ionisation enthalpy =4560 kJ mol−1= 4560\,\text{kJ mol}^{-1}=4560kJ mol−1

There is a very large jump from the first to the second ionisation enthalpy. This means that after losing one electron, the metal attains a stable noble gas configuration.

So the metal is a Group 1 metal and forms a monovalent ion: M→M++e−M \to M^+ + e^-M→M++e−

Hence, its hydroxide will be: MOHMOHMOH


  1. Reaction with HClHClHCl

The reaction is: MOH+HCl→MCl+H2OMOH + HCl \to MCl + H_2OMOH+HCl→MCl+H2​O

From the equation,

  • 111 mole of MOHMOHMOH reacts with 111 mole of HClHClHCl

So for 111 mole of metal hydroxide, required HCl=1HCl = 1HCl=1 mole.


  1. Reaction with H2SO4H_2SO_4H2​SO4​

Since H2SO4H_2SO_4H2​SO4​ is dibasic, the balanced reaction is: 2MOH+H2SO4→M2SO4+2H2O2MOH + H_2SO_4 \to M_2SO_4 + 2H_2O2MOH+H2​SO4​→M2​SO4​+2H2​O

From the equation,

  • 222 moles of MOHMOHMOH react with 111 mole of H2SO4H_2SO_4H2​SO4​

Therefore, for 111 mole of MOHMOHMOH, required H2SO4H_2SO_4H2​SO4​ is: 12 mole=0.5 mole\frac{1}{2}\text{ mole} = 0.5\text{ mole}21​ mole=0.5 mole


  1. Final answer

Thus, the required moles of HClHClHCl and H2SO4H_2SO_4H2​SO4​, respectively, are: 1 and 0.51 \text{ and } 0.51 and 0.5

So the correct option is B.

PreviousNext

More from Periodic Table and Periodicity

  • The lathanide ion that would show colour is :2019 · MCQ
  • The size of the iso-electronic species Cl−, Ar and Ca2+ is affected by :2019 · MCQ
  • The IUPAC symbol for the element with atomic number 119 would be :2019 · MCQ
  • The element having greatest difference between its first and second ionization energies, is :2019 · MCQ
  • Aluminium is usually found in +3 oxidation state. In contrast, thallium exists in + 1 and + 3 oxidation states. This is due to :2019 · MCQ
  • In general, the properties that decrease and increase down a group in the periodic table, respectively, are :2019 · MCQ
  • When the first electron gain enthalpy (Δeg​H) of oxygen is − 141 kJ/mol, its second electron gain enthalpy is :2019 · MCQ
  • The electronegativity of aluminium is similar to :2019 · MCQ