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Periodic Table and Periodicity question

2019 · 9 Jan · Shift 1 · Q19
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Periodic Table and Periodicity question

2019 · 9 Jan · Shift 1 · Q19

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Aluminium is usually found in +3 oxidation state. In contrast, thallium exists in + 1 and + 3 oxidation states. This is due to :
  1. A
    inert pair effect
  2. B
    diagonal relationship
  3. C
    lattice structure
  4. D
    lanthanoid contraction
View written solutionFree

Correct answer: A

  1. Identify the concept involved

    Aluminium and thallium both belong to Group 13 of the periodic table.

    • Aluminium commonly shows oxidation state +3+3+3.
    • Thallium shows both +1+1+1 and +3+3+3, but the +1+1+1 state is especially stable.
  2. Reason for anomalous behavior of thallium

    Thallium has outer electronic configuration: [Xe]4f145d106s26p1[Xe]4f^{14}5d^{10}6s^26p^1[Xe]4f145d106s26p1

    In heavy p-block elements like thallium, the outermost ns2ns^2ns2 electrons tend to remain less available for bonding due to poor shielding by inner ddd and fff electrons.

    This makes the 6s26s^26s2 electron pair relatively "inert" or reluctant to participate in bonding.

    Hence:

    • Losing only the 6p16p^16p1 electron gives oxidation state +1+1+1.
    • Losing all three valence electrons gives oxidation state +3+3+3.

    The extra stability of +1+1+1 in thallium is due to the inert pair effect.

  3. Check the options

    • A: inert pair effect — Correct.
    • B: diagonal relationship — Not relevant here.
    • C: lattice structure — Not the cause of oxidation state variation.
    • D: lanthanoid contraction — It influences size and some properties, but the direct reason for stability of +1+1+1 in thallium is the inert pair effect.
  4. Final answer

    Therefore, the correct option is: A: inert pair effect\boxed{\text{A: inert pair effect}}A: inert pair effect​

  5. Comparison with stored correct answer

    Stored correct answer: A

    My derived answer: A

    They agree.

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