JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Aluminium is usually found in +3 oxidation state. In contrast, thallium exists in + 1 and + 3 oxidation states. This is due to :
- Ainert pair effect
- Bdiagonal relationship
- Clattice structure
- Dlanthanoid contraction
View written solutionFree
Correct answer: A
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Identify the concept involved
Aluminium and thallium both belong to Group 13 of the periodic table.
- Aluminium commonly shows oxidation state .
- Thallium shows both and , but the state is especially stable.
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Reason for anomalous behavior of thallium
Thallium has outer electronic configuration:
In heavy p-block elements like thallium, the outermost electrons tend to remain less available for bonding due to poor shielding by inner and electrons.
This makes the electron pair relatively "inert" or reluctant to participate in bonding.
Hence:
- Losing only the electron gives oxidation state .
- Losing all three valence electrons gives oxidation state .
The extra stability of in thallium is due to the inert pair effect.
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Check the options
- A: inert pair effect — Correct.
- B: diagonal relationship — Not relevant here.
- C: lattice structure — Not the cause of oxidation state variation.
- D: lanthanoid contraction — It influences size and some properties, but the direct reason for stability of in thallium is the inert pair effect.
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Final answer
Therefore, the correct option is:
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Comparison with stored correct answer
Stored correct answer: A
My derived answer: A
They agree.
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