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P Block Elements question

2025 · 2 Apr · Shift 2 · Q15
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P Block Elements question

2025 · 2 Apr · Shift 2 · Q15

JEE MainChemistryP Block ElementsMCQ+4 / −1
The nature of oxide (TeO2)\left(\mathrm{TeO}_2\right)(TeO2​) and hydride (TeH2)\left(\mathrm{TeH}_2\right)(TeH2​) formed by Te , respectively are :
  1. A
    Reducing and basic
  2. B
    Reducing and acidic
  3. C
    Oxidising and acidic
  4. D
    Oxidising and basic
View written solutionFree

Correct answer: C

  1. Identify the element and its group trend

    Tellurium, Te\mathrm{Te}Te, belongs to Group 16 (chalcogens).

    We need the nature of:

    • oxide: TeO2\mathrm{TeO_2}TeO2​
    • hydride: TeH2\mathrm{TeH_2}TeH2​
  2. Nature of TeO2\mathrm{TeO_2}TeO2​

    In TeO2\mathrm{TeO_2}TeO2​, oxygen is −2-2−2, so Te is in the +4+4+4 oxidation state.

    For heavier p-block elements, lower oxidation states often show both oxidising and reducing behavior, but here the standard textbook trend for Group 16 dioxides is:

    • SO2\mathrm{SO_2}SO2​ is mainly reducing
    • down the group, the dioxides become less reducing and more oxidising

    Thus TeO2\mathrm{TeO_2}TeO2​ is taken as oxidising in character.

  3. Nature of TeH2\mathrm{TeH_2}TeH2​

    Hydrides of Group 16 are: H2O, H2S, H2Se, H2Te\mathrm{H_2O,\ H_2S,\ H_2Se,\ H_2Te}H2​O, H2​S, H2​Se, H2​Te

    Their acidic character increases down the group because the E−H\mathrm{E-H}E−H bond weakens down the group, making release of H+\mathrm{H^+}H+ easier.

    Therefore: H2O<H2S<H2Se<H2Te\mathrm{H_2O < H_2S < H_2Se < H_2Te}H2​O<H2​S<H2​Se<H2​Te in acidic strength.

    So TeH2\mathrm{TeH_2}TeH2​ (i.e. H2Te\mathrm{H_2Te}H2​Te) is acidic.

  4. Match with the options

    • Oxide TeO2\mathrm{TeO_2}TeO2​: oxidising
    • Hydride TeH2\mathrm{TeH_2}TeH2​: acidic

    Hence the correct option is: C: Oxidising and acidic\boxed{\text{C: Oxidising and acidic}}C: Oxidising and acidic​

  5. Comparison with stored answer

    Stored correct answer: C

    Our derived answer is also C, so they agree.

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