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P Block Elements question

2024 · 1 Feb · Shift 2 · Q12
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P Block Elements question

2024 · 1 Feb · Shift 2 · Q12

JEE MainChemistryP Block ElementsMCQ+4 / −1
The strongest reducing agent among the following is :
  1. A
    SbH3\mathrm{SbH}_3SbH3​
  2. B
    NH3\mathrm{NH}_3NH3​
  3. C
    BiH3\mathrm{BiH}_3BiH3​
  4. D
    PH3\mathrm{PH}_3PH3​
View written solutionFree

Correct answer: C

  1. Identify the species

The given hydrides belong to group 15:

NH3, PH3, SbH3, BiH3\mathrm{NH_3,\ PH_3,\ SbH_3,\ BiH_3}NH3​, PH3​, SbH3​, BiH3​

  1. Relevant trend in group 15 hydrides

As we move down the group from nitrogen to bismuth:

  • Atomic size increases
  • The E−HE-HE−H bond strength decreases
  • The hydrides become less stable
  • Hence they more readily donate hydrogen / get oxidized
  • Therefore, reducing character increases down the group

So the reducing power follows:

NH3<PH3<SbH3<BiH3\mathrm{NH_3 < PH_3 < SbH_3 < BiH_3}NH3​<PH3​<SbH3​<BiH3​

  1. Reasoning in terms of bond strength

A reducing agent is one that is easily oxidized. For these hydrides, weaker E−HE-HE−H bonds mean the compound is more unstable and can act as a stronger reducing agent.

Since Bi−H\mathrm{Bi-H}Bi−H bond is the weakest among the given options, BiH3\mathrm{BiH_3}BiH3​ is the strongest reducing agent.

  1. Evaluate options
  • A: SbH3\mathrm{SbH_3}SbH3​ — strong reducing agent, but less than BiH3\mathrm{BiH_3}BiH3​
  • B: NH3\mathrm{NH_3}NH3​ — least reducing among these
  • C: BiH3\mathrm{BiH_3}BiH3​ — strongest reducing agent
  • D: PH3\mathrm{PH_3}PH3​ — stronger than NH3\mathrm{NH_3}NH3​ but weaker than SbH3\mathrm{SbH_3}SbH3​ and BiH3\mathrm{BiH_3}BiH3​
  1. Final answer

BiH3\boxed{\mathrm{BiH_3}}BiH3​​

So, the correct option is C.

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