- A(A), (B) and (C) Only
- B(A) and (B) Only
- C(C), (D) and (E) Only
- D(C) and (D) Only
View written solutionFree
Correct answer: C
-
Check statement (A): Covalent radius decreases down the group from to in a regular manner.
This is false.
In group 14, atomic/covalent radius generally increases down the group, not decreases.
Order is roughly:
So statement (A) is incorrect.
-
Check statement (B): Electronegativity decreases from to down the group gradually.
This is also false.
In group 14, electronegativity does not decrease regularly down the group. Because of poor shielding by and electrons, the values are somewhat irregular.
Approximate trend:
Hence it does not decrease gradually from to .
-
Check statement (C): Maximum covalence of is 4 whereas other elements can expand their covalence due to presence of d orbitals.
This is true.
- Carbon has no vacant orbitals in its valence shell, so maximum covalency is 4.
- Heavier group 14 elements like Si, Ge, Sn, Pb can show covalency greater than 4 in some compounds due to availability of vacant orbitals (traditionally explained using orbitals in JEE-level chemistry).
Therefore, (C) is correct.
-
Check statement (D): Heavier elements do not form bonds.
This is true.
Carbon readily forms multiple bonds like: because effective sideways overlap of small 2p orbitals is possible.
Heavier elements (Si, Ge, Sn, Pb) have larger and more diffuse orbitals, so effective overlap is poor. Thus they generally do not form such bonds.
Hence (D) is correct.
-
Check statement (E): Carbon can exhibit negative oxidation states.
This is true.
Carbon shows negative oxidation states in compounds with less electronegative elements, for example:
- In methane, , oxidation state of carbon is
- In carbides also carbon may have negative oxidation state.
So (E) is correct.
-
Collect the correct statements
- (A) False
- (B) False
- (C) True
- (D) True
- (E) True
Therefore the correct set is:
-
Match with options
This corresponds to Option C.
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