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P Block Elements question

2024 · 6 Apr · Shift 2 · Q13
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P Block Elements question

2024 · 6 Apr · Shift 2 · Q13

JEE MainChemistryP Block ElementsMCQ+4 / −1
Evaluate the following statements related to group 14 elements for their correctness. (A) Covalent radius decreases down the group from C\mathrm{C}C to Pb\mathrm{Pb}Pb in a regular manner. (B) Electronegativity decreases from C\mathrm{C}C to Pb\mathrm{Pb}Pb down the group gradually. (C) Maximum covalance of C\mathrm{C}C is 4 whereas other elements can expand their covalance due to presence of d orbitals. (D) Heavier elements do not form pπ−pπ\mathrm{p} \pi-\mathrm{p} \pipπ−pπ bonds. (E) Carbon can exhibit negative oxidation states. Choose the correct answer from the options given below :
  1. A
    (A), (B) and (C) Only
  2. B
    (A) and (B) Only
  3. C
    (C), (D) and (E) Only
  4. D
    (C) and (D) Only
View written solutionFree

Correct answer: C

  1. Check statement (A): Covalent radius decreases down the group from C\mathrm{C}C to Pb\mathrm{Pb}Pb in a regular manner.

    This is false.

    In group 14, atomic/covalent radius generally increases down the group, not decreases.

    Order is roughly: C<Si<Ge≈Sn<Pb\mathrm{C} < \mathrm{Si} < \mathrm{Ge} \approx \mathrm{Sn} < \mathrm{Pb}C<Si<Ge≈Sn<Pb

    So statement (A) is incorrect.

  2. Check statement (B): Electronegativity decreases from C\mathrm{C}C to Pb\mathrm{Pb}Pb down the group gradually.

    This is also false.

    In group 14, electronegativity does not decrease regularly down the group. Because of poor shielding by ddd and fff electrons, the values are somewhat irregular.

    Approximate trend: C>Si<Ge≈Sn<Pb\mathrm{C} > \mathrm{Si} < \mathrm{Ge} \approx \mathrm{Sn} < \mathrm{Pb}C>Si<Ge≈Sn<Pb

    Hence it does not decrease gradually from C\mathrm{C}C to Pb\mathrm{Pb}Pb.

  3. Check statement (C): Maximum covalence of C\mathrm{C}C is 4 whereas other elements can expand their covalence due to presence of d orbitals.

    This is true.

    • Carbon has no vacant ddd orbitals in its valence shell, so maximum covalency is 4.
    • Heavier group 14 elements like Si, Ge, Sn, Pb can show covalency greater than 4 in some compounds due to availability of vacant orbitals (traditionally explained using ddd orbitals in JEE-level chemistry).

    Therefore, (C) is correct.

  4. Check statement (D): Heavier elements do not form pπ−pπ\mathrm{p}\pi-\mathrm{p}\pipπ−pπ bonds.

    This is true.

    Carbon readily forms multiple bonds like: C=C,C≡C,C=O\mathrm{C=C}, \quad \mathrm{C\equiv C}, \quad \mathrm{C=O}C=C,C≡C,C=O because effective sideways overlap of small 2p orbitals is possible.

    Heavier elements (Si, Ge, Sn, Pb) have larger and more diffuse orbitals, so effective pπ−pπ\mathrm{p}\pi-\mathrm{p}\pipπ−pπ overlap is poor. Thus they generally do not form such bonds.

    Hence (D) is correct.

  5. Check statement (E): Carbon can exhibit negative oxidation states.

    This is true.

    Carbon shows negative oxidation states in compounds with less electronegative elements, for example:

    • In methane, CH4\mathrm{CH_4}CH4​, oxidation state of carbon is x+4(+1)=0⇒x=−4x + 4(+1) = 0 \Rightarrow x = -4x+4(+1)=0⇒x=−4
    • In carbides also carbon may have negative oxidation state.

    So (E) is correct.

  6. Collect the correct statements

    • (A) False
    • (B) False
    • (C) True
    • (D) True
    • (E) True

    Therefore the correct set is: (C),(D) and (E) only\boxed{(C), (D) \text{ and } (E)\text{ only}}(C),(D) and (E) only​

  7. Match with options

    This corresponds to Option C.

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