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P Block Elements question

2007 · Shift 0 · Q11
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P Block Elements question

2007 · Shift 0 · Q11

JEE MainChemistryP Block ElementsMCQ+4 / −1
The stability of dihalides of Si,Ge,SnSi,Ge,SnSi,Ge,Sn and PbPbPb increases steadily in the sequence :
  1. A
    PbX2<<SnX2<<GeX2<<SiX2Pb{X_2} \lt \lt Sn{X_2} \lt \lt Ge{X_2} \lt \lt Si{X_2}PbX2​<<SnX2​<<GeX2​<<SiX2​
  2. B
    GeX2<<SiX2<<SnX2<<PbX2Ge{X_2} \lt \lt Si{X_2} \lt \lt Sn{X_2} \lt \lt Pb{X_2}GeX2​<<SiX2​<<SnX2​<<PbX2​
  3. C
    SiX2<<GeX2<<PbX2<<SnX2Si{X_2} \lt \lt Ge{X_2} \lt \lt Pb{X_2} \lt \lt Sn{X_2}SiX2​<<GeX2​<<PbX2​<<SnX2​
  4. D
    SiX2<<GeX2<<SnX2<<PbX2Si{X_2} \lt \lt Ge{X_2} \lt \lt Sn{X_2} \lt \lt Pb{X_2}SiX2​<<GeX2​<<SnX2​<<PbX2​
View written solutionFree

Correct answer: D

  1. We are comparing the stability of the dihalides MX2MX_2MX2​ of group 14 elements: Si, Ge, Sn, PbSi,\ Ge,\ Sn,\ PbSi, Ge, Sn, Pb

  2. Group 14 elements show oxidation states +4+4+4 and +2+2+2.

    • For the lighter elements like SiSiSi and GeGeGe, the +4+4+4 state is more stable.
    • For the heavier elements like SnSnSn and especially PbPbPb, the +2+2+2 state becomes increasingly stable.
  3. The reason is the inert pair effect.

    • Down the group, the valence ns2ns^2ns2 electrons become less willing to participate in bonding.
    • Hence, the lower oxidation state +2+2+2 becomes more stable as we move from SiSiSi to PbPbPb.
  4. Therefore, the stability of dihalides MX2MX_2MX2​ increases down the group: SiX2<GeX2<SnX2<PbX2SiX_2 < GeX_2 < SnX_2 < PbX_2SiX2​<GeX2​<SnX2​<PbX2​

  5. Now check the options:

    • A: opposite order, incorrect.
    • B: wrong placement of SiX2SiX_2SiX2​ and GeX2GeX_2GeX2​, incorrect.
    • C: puts PbX2PbX_2PbX2​ less stable than SnX2SnX_2SnX2​, incorrect.
    • D: SiX2≪GeX2≪SnX2≪PbX2SiX_2 \ll GeX_2 \ll SnX_2 \ll PbX_2SiX2​≪GeX2​≪SnX2​≪PbX2​ correct.

Thus, the correct option is D.

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