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P Block Elements question

2004 · Shift 0 · Q44
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P Block Elements question

2004 · Shift 0 · Q44

JEE MainChemistryP Block ElementsMCQ+4 / −1
Beryllium and aluminium exhibit many properties which are similar. But the two elements differ in :
  1. A
    exhibiting maximum covalency in compound
  2. B
    exhibiting amphoteric nature in their oxides
  3. C
    forming covalent halides
  4. D
    forming polymeric hydrides
View written solutionFree

Correct answer: A

  1. Why Be and Al are compared
    Beryllium and aluminium show a diagonal relationship, so they have several similar properties.

  2. Check each option

    Option B: Amphoteric nature of oxides

    • Beryllium oxide: BeO\mathrm{BeO}BeO is amphoteric.
    • Aluminium oxide: Al2O3\mathrm{Al_2O_3}Al2​O3​ is also amphoteric.
    • So this is a similarity, not a difference.

    Option C: Forming covalent halides

    • BeCl2\mathrm{BeCl_2}BeCl2​ is covalent.
    • AlCl3\mathrm{AlCl_3}AlCl3​ is also largely covalent and exists as dimer Al2Cl6\mathrm{Al_2Cl_6}Al2​Cl6​.
    • So this is also a similarity.

    Option D: Forming polymeric hydrides

    • Beryllium forms polymeric hydride: BeH2\mathrm{BeH_2}BeH2​.
    • Aluminium forms polymeric hydride: AlH3\mathrm{AlH_3}AlH3​.
    • Again, this is a similarity.

    Option A: Exhibiting maximum covalency in compound

    • Beryllium has valence shell configuration 2s22s^22s2 and no available d-orbitals, so its maximum covalency is limited to 4.
    • Aluminium can show higher coordination/covalency in species like [AlF6]3−\mathrm{[AlF_6]^{3-}}[AlF6​]3−, so its maximum covalency can be 6.
    • Therefore, this is a difference between Be and Al.
  3. Conclusion The property in which beryllium and aluminium differ is: A: exhibiting maximum covalency in compound\boxed{\text{A: exhibiting maximum covalency in compound}}A: exhibiting maximum covalency in compound​

  4. Comparison with stored answer

    • Derived answer: A
    • Stored correct answer: A
    • They agree.
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