JEE MainChemistryHydrocarbonsMCQ+4 / −1
What is the product when acetylene reacts with hypochlorous acid ?
- A
- B
- C
- DClCHCOOH
View written solutionFree
Correct answer: B
- Identify the reaction type
Acetylene is ethyne, .
Hypochlorous acid is , which adds across a multiple bond. For alkynes, addition of gives a vinyl halohydrin, which then undergoes keto-enol tautomerism to form a carbonyl compound.
- Addition of to acetylene
Across the triple bond of acetylene:
This is the enol form.
- Tautomerism of the enol
The enol tautomerizes to the corresponding aldehyde:
So the product is chloroacetaldehyde.
- Match with options
- A: = acetyl chloride, not formed here
- B: = chloroacetaldehyde, correct
- C: = dichloroacetaldehyde, would require two Cl atoms
- D: = not the product of this addition
- Conclusion
The product formed when acetylene reacts with hypochlorous acid is:
So the correct option is B.
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