JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
The correct order of melting points of dichlorobenzenes is
- A

- B

- C

- D

View written solutionFree
Correct answer: A
- Identify the isomers
Dichlorobenzene has three positional isomers:
- -dichlorobenzene
- -dichlorobenzene
- -dichlorobenzene
We need the correct order of their melting points.
- Key principle: melting point depends strongly on crystal packing
For isomeric aromatic compounds, melting point is not determined only by molecular mass. It depends a lot on how well molecules can pack in the crystal lattice.
- More symmetrical molecules pack better.
- Better packing gives stronger intermolecular attractions in the solid state.
- Hence, more symmetrical isomers generally have higher melting points.
- Compare symmetry of the three isomers
- -dichlorobenzene is the most symmetrical.
- -dichlorobenzene is less symmetrical.
- -dichlorobenzene is also less symmetrical and its adjacent chlorine atoms cause poorer packing.
Therefore, the highest melting point should be for the para isomer.
- Known relative order
The standard order of melting points is:
Approximate values support this:
- -dichlorobenzene: about
- -dichlorobenzene: about
- -dichlorobenzene: about
So,
- Match with stored answer
Since the option texts are not visible, I can only derive the correct order as:
If option A corresponds to this order, then the stored answer is correct.
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