- A

- B

- C

- D

View written solutionFree
Correct answer: C
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Key idea: directing effect in electrophilic aromatic substitution
We need the compound whose halogenation gives the meta-substituted product with respect to the methyl group as the major product.
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Effect of substituents
- A methyl group is ortho/para-directing.
- To get substitution meta with respect to methyl, there must be another substituent already on the ring that is a strong meta-directing group, and its directing influence should dominate.
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Required situation
If a benzene ring contains both:
- a methyl group and
- a strong electron-withdrawing meta-directing group such as , , , , , etc.,
then incoming halogen tends to enter at a position that is meta to the methyl group if that position is simultaneously favored by the stronger meta-directing substituent.
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Typical correct choice
In standard JEE questions of this type, the correct structure is the one where a strong meta director is present along with the methyl group, such as methyl benzoic acid / nitrotoluene / similar ring where the available favored site becomes meta to methyl. Since the actual structures for options A, B, C, D are not displayed here, we infer from the stored answer and the directing-effect rule that option C must correspond to that structure.
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Conclusion
Therefore, the compound in option C will give the meta-substituted product with respect to the methyl group as the major product on halogenation.
Note: The image/structures of options are missing in the text provided. So the choice is based on the directing-effect principle and the given stored key.
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