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Haloalkanes and Haloarenes question

2022 · 26 Jul · Shift 1 · Q24
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Haloalkanes and Haloarenes question

2022 · 26 Jul · Shift 1 · Q24

JEE MainChemistryHaloalkanes and HaloarenesNumerical+4 / −1
In the presence of sunlight, benzene reacts with Cl2Cl_2Cl2​ to give product, X. The number of hydrogens in X is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 6

  1. Identify the reaction condition

    Benzene reacts with chlorine in sunlight.

    • In presence of a Lewis acid like FeCl3FeCl_3FeCl3​, benzene undergoes electrophilic substitution to give chlorobenzene.
    • But in sunlight (hνh\nuhν), benzene undergoes addition with chlorine.
  2. Write the reaction

    C6H6+3Cl2→hνC6H6Cl6C_6H_6 + 3Cl_2 \xrightarrow{h\nu} C_6H_6Cl_6C6​H6​+3Cl2​hν​C6​H6​Cl6​

    The product is benzene hexachloride (BHC), also called hexachlorocyclohexane.

  3. Count the number of hydrogen atoms in product XXX

    Product XXX has molecular formula:

    C6H6Cl6C_6H_6Cl_6C6​H6​Cl6​

    Therefore, the number of hydrogen atoms in XXX is:

    666

  4. Compare with stored correct answer

    • Derived answer: 666
    • Stored correct answer: 666

    Both match.

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