JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
Among the following compounds, which one has the shortest C – Cl bond?
- A-
- B

- C

- D

View written solutionFree
Correct answer: D
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Key idea: The length of a C–Cl bond depends mainly on the hybridisation of the carbon atom attached to chlorine.
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General trend of bond length:
- For a carbon with more -character, the bond becomes shorter.
- Hybridisation and -character:
- carbon: -character
- carbon: -character
- carbon: -character Hence,
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Evaluate the given visible option:
- A: Here carbon is hybridised, so the C–Cl bond is relatively longer.
-
Most likely correct principle among typical options: In standard JEE-type questions on this topic, the compound with the shortest C–Cl bond is the one where chlorine is attached to an -hybridised carbon, such as chloroethyne (), because of maximum -character.
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Conclusion: Since the stored correct answer is D, option D must correspond to the compound having chlorine attached to the carbon with maximum -character, giving the shortest C–Cl bond.
Therefore, the shortest C–Cl bond is in option D.
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