Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Electrochemistry question

2025 · 23 Jan · Shift 1 · Q5
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Electrochemistry
  5. /2025 · 23 Jan · Shift 1 · Q5

Electrochemistry question

2025 · 23 Jan · Shift 1 · Q5

JEE MainChemistryElectrochemistryMCQ+4 / −1
FeO42−→+2.0 VFe3+→0.8 VFe2+→−0.5 VFe0\mathrm{FeO}_4^{2-} \xrightarrow{+2.0 \mathrm{~V}} \mathrm{Fe}^{3+} \xrightarrow{0.8 \mathrm{~V}} \mathrm{Fe}^{2+} \xrightarrow{-0.5 \mathrm{~V}} \mathrm{Fe}^0FeO42−​+2.0 V​Fe3+0.8 V​Fe2+−0.5 V​Fe0 In the above diagram, the standard electrode potentials are given in volts (over the arrow). The value of EFeO42−/Fe2+\mathrm{E}_{\mathrm{FeO}_4^{2-} / \mathrm{Fe}^{2+}}EFeO42−​/Fe2+​ is :
  1. A
    1.2 V
  2. B
    2.1 V
  3. C
    1.4 V
  4. D
    1.7 V
View written solutionFree

Correct answer: D

  1. Write the given standard reduction steps

From the diagram:

FeO42−→+2.0 VFe3+→0.8 VFe2+→−0.5 VFe0\mathrm{FeO}_4^{2-} \xrightarrow{+2.0\,V} \mathrm{Fe}^{3+} \xrightarrow{0.8\,V} \mathrm{Fe}^{2+} \xrightarrow{-0.5\,V} \mathrm{Fe}^0FeO42−​+2.0V​Fe3+0.8V​Fe2+−0.5V​Fe0

we interpret the first two relevant reduction half-reactions as:

FeO42−+8H++3e−→Fe3++4H2OE∘=2.0 V\mathrm{FeO}_4^{2-} + 8H^+ + 3e^- \rightarrow \mathrm{Fe}^{3+} + 4H_2O \qquad E^\circ = 2.0\,VFeO42−​+8H++3e−→Fe3++4H2​OE∘=2.0V

and

Fe3++e−→Fe2+E∘=0.8 V\mathrm{Fe}^{3+} + e^- \rightarrow \mathrm{Fe}^{2+} \qquad E^\circ = 0.8\,VFe3++e−→Fe2+E∘=0.8V

We need E∘E^\circE∘ for:

FeO42−+8H++4e−→Fe2++4H2O\mathrm{FeO}_4^{2-} + 8H^+ + 4e^- \rightarrow \mathrm{Fe}^{2+} + 4H_2OFeO42−​+8H++4e−→Fe2++4H2​O

  1. Use the relation involving Gibbs energy

Standard electrode potentials are not added directly unless the number of electrons is same. We use:

ΔG∘=−nFE∘\Delta G^\circ = -nFE^\circΔG∘=−nFE∘

For the first step:

ΔG1∘=−3F(2.0)=−6.0F\Delta G_1^\circ = -3F(2.0) = -6.0FΔG1∘​=−3F(2.0)=−6.0F

For the second step:

ΔG2∘=−1F(0.8)=−0.8F\Delta G_2^\circ = -1F(0.8) = -0.8FΔG2∘​=−1F(0.8)=−0.8F

Adding them:

ΔGtotal∘=−6.0F−0.8F=−6.8F\Delta G_{\text{total}}^\circ = -6.0F -0.8F = -6.8FΔGtotal∘​=−6.0F−0.8F=−6.8F

  1. Find the overall electrode potential

The overall reaction involves 444 electrons, so

ΔGtotal∘=−4FEFeO42−/Fe2+∘\Delta G_{\text{total}}^\circ = -4F E^\circ_{\mathrm{FeO}_4^{2-}/\mathrm{Fe}^{2+}}ΔGtotal∘​=−4FEFeO42−​/Fe2+∘​

Thus,

−4FE∘=−6.8F-4F E^\circ = -6.8F−4FE∘=−6.8F

E∘=6.84=1.7 VE^\circ = \frac{6.8}{4} = 1.7\,VE∘=46.8​=1.7V

  1. Match with options

EFeO42−/Fe2+∘=1.7 VE^\circ_{\mathrm{FeO}_4^{2-}/\mathrm{Fe}^{2+}} = 1.7\,VEFeO42−​/Fe2+∘​=1.7V

So the correct option is:

D: 1.7 V1.7\,V1.7V

PreviousNext

More from Electrochemistry

  • Standard electrode potentials for a few half cells are mentioned below : ​ECu2+/Cu∘​=0.34 V,EZn2+/Zn∘​=−0.76 VEAg+/Ag∘​=0.80 V,EMg2+/Mg∘​=−2.37 V​…2025 · MCQ
  • For the given cell Fe2+(aq)+Ag(aq)+​→Fe3+(aq)+Ag(s)​ The standard cell potential of the above reaction is Given: Ag++e−→AgFe2++2e−→FeFe3++3e−→Fe​Eθ=xVEθ=yVEθ=zV​…2025 · MCQ
  • Based on the data given below : ECr2​O72−​/Cr3+∘​=1.33 VEMnO4−​/Mn2+0​=1.51 V​ECl2​/Cl(−)∘​=1.36 VECr3+/Cr∘​=−0.74 V​…2025 · MCQ
  • Given below is the plot of the molar conductivity vs  concentration ​ for KCl in aqueous solution. If, for the higher concentration of KCl solution, the resistance of the conductivity cell is 100Ω, then the… Includes diagram2025 · Numerical
  • Electrolysis of 600 mL aqueous solution of NaCl for 5 min changes the pH of the solution to 12 . The current in Amperes used for the given electrolysis is ​ . (Nearest integer).2025 · Numerical
  • The standard reduction potential values of some of the p-block ions are given below. Predict the one with the strongest oxidising capacity.2025 · MCQ
  • For a Mg | Mg2+ (aq) || Ag+ (aq) | Ag the correct Nernst Equation is :2025 · MCQ
  • The molar conductivity of a weak electrolyte when plotted against the square root of its concentration, which of the following is expected to be observed?2025 · MCQ