Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Electrochemistry question

2025 · 29 Jan · Shift 1 · Q10
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Electrochemistry
  5. /2025 · 29 Jan · Shift 1 · Q10

Electrochemistry question

2025 · 29 Jan · Shift 1 · Q10

JEE MainChemistryElectrochemistryMCQ+4 / −1
The standard reduction potential values of some of the p-block ions are given below. Predict the one with the strongest oxidising capacity.
  1. A
    ESn4+/Sn2+o=+1.15 VE^o_{\text{Sn}^{4+}/\text{Sn}^{2+}} = +1.15 \text{ V}ESn4+/Sn2+o​=+1.15 V
  2. B
    EAl3+/Alo=−1.66 VE^o_{\text{Al}^{3+}/\text{Al}} = -1.66 \text{ V}EAl3+/Alo​=−1.66 V
  3. C
    EPb4+/Pb2+o=+1.67 VE^o_{\text{Pb}^{4+}/\text{Pb}^{2+}} = +1.67 \text{ V}EPb4+/Pb2+o​=+1.67 V
  4. D
    ETl3+/Tlo=+1.26 VE^o_{\text{Tl}^{3+}/\text{Tl}} = +1.26 \text{ V}ETl3+/Tlo​=+1.26 V
View written solutionFree

Correct answer: C

  1. Concept used

    The strongest oxidising agent is the species which gets reduced most easily.

    In electrochemistry, this corresponds to the largest positive standard reduction potential E∘E^\circE∘.

  2. Given reduction potentials

    • A: Sn4++2e−→Sn2+\mathrm{Sn^{4+} + 2e^- \rightarrow Sn^{2+}}Sn4++2e−→Sn2+, E∘=+1.15 VE^\circ = +1.15\,\text{V}E∘=+1.15V
    • B: Al3++3e−→Al\mathrm{Al^{3+} + 3e^- \rightarrow Al}Al3++3e−→Al, E∘=−1.66 VE^\circ = -1.66\,\text{V}E∘=−1.66V
    • C: Pb4++2e−→Pb2+\mathrm{Pb^{4+} + 2e^- \rightarrow Pb^{2+}}Pb4++2e−→Pb2+, E∘=+1.67 VE^\circ = +1.67\,\text{V}E∘=+1.67V
    • D: Tl3++3e−→Tl\mathrm{Tl^{3+} + 3e^- \rightarrow Tl}Tl3++3e−→Tl, E∘=+1.26 VE^\circ = +1.26\,\text{V}E∘=+1.26V
  3. Compare the values

    The values are: +1.15,  −1.66,  +1.67,  +1.26+1.15,\;-1.66,\;+1.67,\;+1.26+1.15,−1.66,+1.67,+1.26

    The highest reduction potential is: +1.67 V+1.67\,\text{V}+1.67V

  4. Inference

    Therefore, the species with the greatest tendency to get reduced, and hence the strongest oxidising capacity, is: Pb4+\mathrm{Pb^{4+}}Pb4+

  5. Option check

    • A: weaker than C
    • B: negative potential, so not a strong oxidising agent
    • C: maximum positive E∘E^\circE∘ → strongest oxidising agent
    • D: positive, but less than C

Final Answer: C

PreviousNext

More from Electrochemistry

  • For a Mg | Mg2+ (aq) || Ag+ (aq) | Ag the correct Nernst Equation is :2025 · MCQ
  • The molar conductivity of a weak electrolyte when plotted against the square root of its concentration, which of the following is expected to be observed?2025 · MCQ
  • O2​ gas will be evolved as a product of electrolysis of : (A) an aqueous solution of AgNO3​ using silver electrodes. (B) an aqueous solution of AgNO3​ using platinum electrodes. (C) a dilute solution of H2​SO4​…2025 · MCQ
  • Match List - I with List - II : Choose the correct answer from the options given below : Includes table2025 · MCQ
  • The potential for the given half cell at 298 K is (-) ​×10−2 V ​2H(aq)+​+2e−⟶H2​( g)[H+]=1M,PH2​​=2 atm​…2024 · Numerical
  • The amount of electricity in Coulomb required for the oxidation of 1 mol of H2​O to O2​ is ​×105C.2024 · Numerical
  • Consider the following redox reaction : MnO4−​+H++H2​C2​O4​⇌Mn2++H2​O+CO2​ The standard reduction potentials are given as…2024 · Numerical
  • One of the commonly used electrode is calomel electrode. Under which of the following categories, calomel electrode comes?2024 · MCQ