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Electrochemistry question

2025 · 23 Jan · Shift 2 · Q14
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  5. /2025 · 23 Jan · Shift 2 · Q14

Electrochemistry question

2025 · 23 Jan · Shift 2 · Q14

JEE MainChemistryElectrochemistryMCQ+4 / −1
Standard electrode potentials for a few half cells are mentioned below : ECu2+/Cu∘=0.34 V,EZn2+/Zn∘=−0.76 VEAg+/Ag∘=0.80 V,EMg2+/Mg∘=−2.37 V\begin{aligned} & \mathrm{E}_{\mathrm{Cu}^{2+} / \mathrm{Cu}}^{\circ}=0.34 \mathrm{~V}, \mathrm{E}_{\mathrm{Zn}^{2+} / \mathrm{Zn}}^{\circ}=-0.76 \mathrm{~V} \\ & \mathrm{E}_{\mathrm{Ag}^{+} / \mathrm{Ag}}^{\circ}=0.80 \mathrm{~V}, \mathrm{E}_{\mathrm{Mg}^{2+} / \mathrm{Mg}}^{\circ}=-2.37 \mathrm{~V} \end{aligned}​ECu2+/Cu∘​=0.34 V,EZn2+/Zn∘​=−0.76 VEAg+/Ag∘​=0.80 V,EMg2+/Mg∘​=−2.37 V​ Which one of the following cells gives the most negative value of ΔG∘\Delta \mathrm{G}^{\circ}ΔG∘ ?
  1. A
    Zn∣Zn2+(1M)∥Ag+(1M)∣Ag\mathrm{Zn}\left|\mathrm{Zn}^{2+}(1 \mathrm{M}) \| \mathrm{Ag}^{+}(1 \mathrm{M})\right| \mathrm{Ag}Zn​Zn2+(1M)∥Ag+(1M)​Ag
  2. B
    Ag∣Ag+(1M)∣∣Mg2+(1M)∣Mg\mathrm{Ag}\left|\mathrm{Ag}^{+}(1 \mathrm{M})\right|\left|\mathrm{Mg}^{2+}(1 \mathrm{M})\right| \mathrm{Mg}Ag​Ag+(1M)​​Mg2+(1M)​Mg
  3. C
    Zn∣Zn2+(1M)∣∣Mg2+(1M)∣Mg\mathrm{Zn}\left|\mathrm{Zn}^{2+}(1 \mathrm{M})\right|\left|\mathrm{Mg}^{2+}(1 \mathrm{M})\right| \mathrm{Mg}Zn​Zn2+(1M)​​Mg2+(1M)​Mg
  4. D
    Cu∣Cu2+(1M)∣∣Ag+(1M)∣Ag\mathrm{Cu}\left|\mathrm{Cu}^{2+}(1 \mathrm{M})\right|\left|\mathrm{Ag}^{+}(1 \mathrm{M})\right| \mathrm{Ag}Cu​Cu2+(1M)​​Ag+(1M)​Ag
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