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Electrochemistry question

2024 · 31 Jan · Shift 1 · Q26
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  5. /2024 · 31 Jan · Shift 1 · Q26

Electrochemistry question

2024 · 31 Jan · Shift 1 · Q26

JEE MainChemistryElectrochemistryNumerical+4 / −1
One Faraday of electricity liberates x×10−1x \times 10^{-1}x×10−1 gram atom of copper from copper sulphate. xxx is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 5

  1. Use Faraday’s law of electrolysis

    One Faraday of charge deposits one gram-equivalent of a substance.

  2. For copper deposition from copper sulphate

    Copper is deposited as: Cu2++2e−→Cu\text{Cu}^{2+} + 2e^- \rightarrow \text{Cu}Cu2++2e−→Cu

    So, copper requires 222 moles of electrons per mole of Cu.

  3. Amount deposited by 1 Faraday

    Since 111 Faraday =1= 1=1 mole of electrons, the amount of copper deposited is: 12 mole of Cu\frac{1}{2} \text{ mole of Cu}21​ mole of Cu

    Now, 111 gram-atom of copper =1= 1=1 mole of copper. Hence, deposited copper =0.5= 0.5=0.5 gram-atom.

  4. Match with the given form

    Given: x×10−1=0.5x \times 10^{-1} = 0.5x×10−1=0.5

    x×0.1=0.5x \times 0.1 = 0.5x×0.1=0.5

    x=5x = 5x=5

  5. Final answer

    5\boxed{5}5​

  6. Comparison with stored correct answer

    Stored correct answer = 555

    This matches the derived answer.

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