- A
- B
- C
- D
View written solutionFree
Correct answer: B
- Given overall reaction
We need the galvanic cell in which the net reaction is
So we should identify the two half-cells that combine to give this reaction.
- Write the relevant half-reactions
(i) Hydrogen electrode
Oxidation of hydrogen is:
This requires a hydrogen electrode:
(ii) Silver-silver chloride electrode
Reduction of silver chloride is:
This requires the electrode:
- Add the half-reactions
Adding
and
we get
This matches the given reaction exactly.
So the cell must contain:
- a hydrogen electrode in acidic medium,
- a silver-silver chloride electrode in chloride-containing medium.
- Check each option
Option A
This has:
- one electrode,
- one electrode,
- no hydrogen electrode.
So it cannot produce the required reaction involving and .
❌ A is incorrect.
Option B
Left electrode:
since provides .
Right electrode:
in chloride medium (again supplied by ), so the half-reaction is
Combining with hydrogen oxidation gives exactly the required net reaction.
✅ B is correct.
Option C
Here the silver electrode is , whose half-reaction is
Combining with hydrogen oxidation would give
This does not involve and as in the given reaction.
❌ C is incorrect.
Option D
Here the solution is , which provides but no for a hydrogen electrode. A hydrogen electrode requires acidic medium containing .
So this does not represent the required half-cell for
❌ D is incorrect.
- Final answer
The correct galvanic cell is:
So the correct option is B.
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