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Electrochemistry question

2023 · 8 Apr · Shift 1 · Q10
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  5. /2023 · 8 Apr · Shift 1 · Q10

Electrochemistry question

2023 · 8 Apr · Shift 1 · Q10

JEE MainChemistryElectrochemistryMCQ+4 / −1
The reaction 12H2( g)+AgCl(s)⇌H+(aq)+Cl−(aq)+Ag(s)\frac{1}{2} \mathrm{H}_{2}(\mathrm{~g})+\mathrm{AgCl}(\mathrm{s}) \rightleftharpoons \mathrm{H}^{+}(\mathrm{aq})+\mathrm{Cl}^{-}(\mathrm{aq})+\mathrm{Ag}(\mathrm{s})21​H2​( g)+AgCl(s)⇌H+(aq)+Cl−(aq)+Ag(s) occurs in which of the given galvanic cell.
  1. A
    Ag∣AgCl(s)∣KCl(soln)∣AgNO3∣Ag\mathrm{Ag}|\mathrm{AgCl}(\mathrm{s})| \mathrm{KCl}\left(\mathrm{sol}^{\mathrm{n}}\right)\left|\mathrm{AgNO}_{3}\right| \mathrm{Ag}Ag∣AgCl(s)∣KCl(soln)∣AgNO3​∣Ag
  2. B
    Pt∣H2( g)∣HCl(soln)∣AgCl(s)∣Ag\mathrm{Pt}\left|\mathrm{H}_{2}(\mathrm{~g})\right| \mathrm{HCl}\left(\mathrm{sol}^{\mathrm{n}}\right)|\mathrm{AgCl}(\mathrm{s})| \mathrm{Ag}Pt∣H2​( g)∣HCl(soln)∣AgCl(s)∣Ag
  3. C
    Pt∣H2( g)∣HCl(soln)∣AgNO3(soln)∣Ag\mathrm{Pt}\left|\mathrm{H}_{2}(\mathrm{~g})\right| \mathrm{HCl}\left(\mathrm{sol}^{\mathrm{n}}\right)\left|\mathrm{AgNO}_{3}\left(\mathrm{sol}^{\mathrm{n}}\right)\right| \mathrm{Ag}Pt∣H2​( g)∣HCl(soln)∣AgNO3​(soln)∣Ag
  4. D
    Pt∣H2( g)∣KCl(soln)∣AgCl(s)∣Ag\mathrm{Pt}\left|\mathrm{H}_{2}(\mathrm{~g})\right| \mathrm{KCl}\left(\mathrm{sol}^{\mathrm{n}}\right)|\mathrm{AgCl}(\mathrm{s})| \mathrm{Ag}Pt∣H2​( g)∣KCl(soln)∣AgCl(s)∣Ag
View written solutionFree

Correct answer: B

  1. Given overall reaction

We need the galvanic cell in which the net reaction is

12H2(g)+AgCl(s)⇌H+(aq)+Cl−(aq)+Ag(s)\frac{1}{2}H_2(g) + AgCl(s) \rightleftharpoons H^+(aq) + Cl^-(aq) + Ag(s)21​H2​(g)+AgCl(s)⇌H+(aq)+Cl−(aq)+Ag(s)

So we should identify the two half-cells that combine to give this reaction.


  1. Write the relevant half-reactions

(i) Hydrogen electrode

Oxidation of hydrogen is:

12H2(g)→H+(aq)+e−\frac{1}{2}H_2(g) \rightarrow H^+(aq) + e^-21​H2​(g)→H+(aq)+e−

This requires a hydrogen electrode:

Pt∣H2(g)∣H+(aq)\text{Pt} | H_2(g) | H^+(aq)Pt∣H2​(g)∣H+(aq)

(ii) Silver-silver chloride electrode

Reduction of silver chloride is:

AgCl(s)+e−→Ag(s)+Cl−(aq)AgCl(s) + e^- \rightarrow Ag(s) + Cl^-(aq)AgCl(s)+e−→Ag(s)+Cl−(aq)

This requires the electrode:

Ag∣AgCl(s)∣Cl−(aq)Ag | AgCl(s) | Cl^-(aq)Ag∣AgCl(s)∣Cl−(aq)


  1. Add the half-reactions

Adding

12H2(g)→H+(aq)+e−\frac{1}{2}H_2(g) \rightarrow H^+(aq) + e^-21​H2​(g)→H+(aq)+e−

and

AgCl(s)+e−→Ag(s)+Cl−(aq)AgCl(s) + e^- \rightarrow Ag(s) + Cl^-(aq)AgCl(s)+e−→Ag(s)+Cl−(aq)

we get

12H2(g)+AgCl(s)→H+(aq)+Cl−(aq)+Ag(s)\frac{1}{2}H_2(g) + AgCl(s) \rightarrow H^+(aq) + Cl^-(aq) + Ag(s)21​H2​(g)+AgCl(s)→H+(aq)+Cl−(aq)+Ag(s)

This matches the given reaction exactly.

So the cell must contain:

  • a hydrogen electrode in acidic medium,
  • a silver-silver chloride electrode in chloride-containing medium.

  1. Check each option

Option A

Ag∣AgCl(s)∣KCl(soln)∣AgNO3∣AgAg|AgCl(s)|KCl(\text{soln})|AgNO_3|AgAg∣AgCl(s)∣KCl(soln)∣AgNO3​∣Ag

This has:

  • one Ag/AgClAg/AgClAg/AgCl electrode,
  • one Ag+/AgAg^+/AgAg+/Ag electrode,
  • no hydrogen electrode.

So it cannot produce the required reaction involving 12H2\frac{1}{2}H_221​H2​ and H+H^+H+.

❌ A is incorrect.


Option B

Pt∣H2(g)∣HCl(soln)∣AgCl(s)∣AgPt|H_2(g)|HCl(\text{soln})|AgCl(s)|AgPt∣H2​(g)∣HCl(soln)∣AgCl(s)∣Ag

Left electrode:

Pt∣H2(g)∣H+(aq)Pt|H_2(g)|H^+(aq)Pt∣H2​(g)∣H+(aq)

since HClHClHCl provides H+H^+H+.

Right electrode:

AgCl(s)∣AgAgCl(s)|AgAgCl(s)∣Ag

in chloride medium (again supplied by HClHClHCl), so the half-reaction is

AgCl(s)+e−→Ag(s)+Cl−(aq)AgCl(s)+e^-\rightarrow Ag(s)+Cl^-(aq)AgCl(s)+e−→Ag(s)+Cl−(aq)

Combining with hydrogen oxidation gives exactly the required net reaction.

✅ B is correct.


Option C

Pt∣H2(g)∣HCl(soln)∣AgNO3(soln)∣AgPt|H_2(g)|HCl(\text{soln})|AgNO_3(\text{soln})|AgPt∣H2​(g)∣HCl(soln)∣AgNO3​(soln)∣Ag

Here the silver electrode is Ag+/AgAg^+/AgAg+/Ag, whose half-reaction is

Ag+(aq)+e−→Ag(s)Ag^+(aq)+e^-\rightarrow Ag(s)Ag+(aq)+e−→Ag(s)

Combining with hydrogen oxidation would give

12H2(g)+Ag+(aq)→H+(aq)+Ag(s)\frac{1}{2}H_2(g)+Ag^+(aq)\rightarrow H^+(aq)+Ag(s)21​H2​(g)+Ag+(aq)→H+(aq)+Ag(s)

This does not involve AgCl(s)AgCl(s)AgCl(s) and Cl−Cl^-Cl− as in the given reaction.

❌ C is incorrect.


Option D

Pt∣H2(g)∣KCl(soln)∣AgCl(s)∣AgPt|H_2(g)|KCl(\text{soln})|AgCl(s)|AgPt∣H2​(g)∣KCl(soln)∣AgCl(s)∣Ag

Here the solution is KClKClKCl, which provides Cl−Cl^-Cl− but no H+H^+H+ for a hydrogen electrode. A hydrogen electrode requires acidic medium containing H+H^+H+.

So this does not represent the required half-cell for

12H2(g)→H+(aq)+e−\frac{1}{2}H_2(g)\rightarrow H^+(aq)+e^-21​H2​(g)→H+(aq)+e−

❌ D is incorrect.


  1. Final answer

The correct galvanic cell is:

Pt∣H2(g)∣HCl(soln)∣AgCl(s)∣Ag\boxed{Pt|H_2(g)|HCl(\text{soln})|AgCl(s)|Ag}Pt∣H2​(g)∣HCl(soln)∣AgCl(s)∣Ag​

So the correct option is B.

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