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Electrochemistry question

2023 · 15 Apr · Shift 1 · Q17
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Electrochemistry question

2023 · 15 Apr · Shift 1 · Q17

JEE MainChemistryElectrochemistryNumerical+4 / −1
The number of correct statements from the following is ‾\underline{\hspace{2cm}}​. (A) Conductivity always decreases with decrease in concentration for both strong and weak electrolytes. (B) The number of ions per unit volume that carry current in a solution increases on dilution. (C) Molar conductivity increases with decrease in concentration (D) The variation in molar conductivity is different for strong and weak electrolytes (E) For weak electrolytes, the change in molar conductivity with dilution is due to decrease in degree of dissociation.
Numerical answer
View written solutionFree

Correct answer: 3

  1. Recall the key definitions

    • Conductivity (κ)(\kappa)(κ) depends on the number of ions present per unit volume.
    • Molar conductivity (Λm)(\Lambda_m)(Λm​) is given by Λm=κ×1000C\Lambda_m = \frac{\kappa \times 1000}{C}Λm​=Cκ×1000​ where CCC is concentration in mol L−1\text{mol L}^{-1}mol L−1.
  2. Evaluate each statement

    (A) Conductivity always decreases with decrease in concentration for both strong and weak electrolytes.

    • On dilution, the number of ions per unit volume decreases.
    • Hence, conductivity κ\kappaκ decreases for both strong and weak electrolytes.
    • So, (A) is correct.

    (B) The number of ions per unit volume that carry current in a solution increases on dilution.

    • On dilution, volume increases, so ions become more spread out.
    • Therefore, the number of ions per unit volume decreases, not increases.
    • So, (B) is incorrect.

    (C) Molar conductivity increases with decrease in concentration.

    • As concentration decreases, interionic interactions reduce.
    • Therefore, each mole of electrolyte contributes more effectively to conduction.
    • Hence, Λm\Lambda_mΛm​ increases on dilution for both strong and weak electrolytes.
    • So, (C) is correct.

    (D) The variation in molar conductivity is different for strong and weak electrolytes.

    • For strong electrolytes, Λm\Lambda_mΛm​ increases only slightly with dilution.
    • For weak electrolytes, Λm\Lambda_mΛm​ increases sharply due to increased dissociation.
    • Thus, the variation is indeed different.
    • So, (D) is correct.

    (E) For weak electrolytes, the change in molar conductivity with dilution is due to decrease in degree of dissociation.

    • For weak electrolytes, dilution causes increase in degree of dissociation, not decrease.
    • This increase is why molar conductivity rises sharply.
    • So, (E) is incorrect.
  3. Count correct statements

    Correct statements are: A, C, DA,\ C,\ DA, C, D

    Number of correct statements: 333

  4. Comparison with stored answer

    Stored correct answer = 333

    Our derived answer also = 333.

    Hence, the answer agrees with the stored answer.

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