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D and F Block Elements question

2024 · 6 Apr · Shift 1 · Q29
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D and F Block Elements question

2024 · 6 Apr · Shift 1 · Q29

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
Among CrO,Cr2O3\mathrm{CrO}, \mathrm{Cr}_2 \mathrm{O}_3CrO,Cr2​O3​ and CrO3\mathrm{CrO}_3CrO3​, the sum of spin-only magnetic moment values of basic and amphoteric oxides is ‾10−2BM\underline{\hspace{2cm}}10^{-2} \mathrm{BM}​10−2BM(nearest integer). (Given atomic number of Cr\mathrm{Cr}Cr is 24 )
Numerical answer
View written solutionFree

Correct answer: 877

  1. Identify nature of the oxides

For chromium oxides:

  • CrO\mathrm{CrO}CrO : chromium is in +2+2+2 oxidation state, and this oxide is basic.
  • Cr2O3\mathrm{Cr_2O_3}Cr2​O3​ : chromium is in +3+3+3 oxidation state, and this oxide is amphoteric.
  • CrO3\mathrm{CrO_3}CrO3​ : chromium is in +6+6+6 oxidation state, and this oxide is acidic.

So we need the sum of spin-only magnetic moments of:

  • CrO\mathrm{CrO}CrO
  • Cr2O3\mathrm{Cr_2O_3}Cr2​O3​

  1. Find electronic configuration of chromium and its ions

Atomic number of Cr = 24

Ground state of Cr: Cr=[Ar] 3d54s1\mathrm{Cr} = [\mathrm{Ar}]\,3d^5 4s^1Cr=[Ar]3d54s1

(a) In CrO\mathrm{CrO}CrO

Oxygen is −2-2−2, so chromium is +2+2+2.

Cr2+=[Ar] 3d4\mathrm{Cr^{2+}} = [\mathrm{Ar}]\,3d^4Cr2+=[Ar]3d4

Thus number of unpaired electrons: n=4n = 4n=4

Spin-only magnetic moment: μ=n(n+2)\mu = \sqrt{n(n+2)}μ=n(n+2)​ μ=4(4+2)=24≈4.899 BM\mu = \sqrt{4(4+2)} = \sqrt{24} \approx 4.899\ \mathrm{BM}μ=4(4+2)​=24​≈4.899 BM


(b) In Cr2O3\mathrm{Cr_2O_3}Cr2​O3​

Let oxidation state of Cr be xxx: 2x+3(−2)=02x + 3(-2) = 02x+3(−2)=0 2x−6=02x - 6 = 02x−6=0 x=+3x = +3x=+3

So chromium is Cr3+\mathrm{Cr^{3+}}Cr3+.

Cr3+=[Ar] 3d3\mathrm{Cr^{3+}} = [\mathrm{Ar}]\,3d^3Cr3+=[Ar]3d3

Thus number of unpaired electrons: n=3n = 3n=3

Spin-only magnetic moment: μ=3(3+2)=15≈3.873 BM\mu = \sqrt{3(3+2)} = \sqrt{15} \approx 3.873\ \mathrm{BM}μ=3(3+2)​=15​≈3.873 BM


  1. Add the required magnetic moments

μtotal=24+15\mu_{\text{total}} = \sqrt{24} + \sqrt{15}μtotal​=24​+15​ μtotal≈4.899+3.873=8.772 BM\mu_{\text{total}} \approx 4.899 + 3.873 = 8.772\ \mathrm{BM}μtotal​≈4.899+3.873=8.772 BM


  1. Convert into the asked form

The question asks for:

‾×10−2 BM\underline{\hspace{2cm}} \times 10^{-2}\ \mathrm{BM}​×10−2 BM

Since 8.772 BM=877.2×10−2 BM8.772\ \mathrm{BM} = 877.2 \times 10^{-2}\ \mathrm{BM}8.772 BM=877.2×10−2 BM

Nearest integer: 877877877


  1. Final answer

877\boxed{877}877​

This matches the stored correct answer.

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