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D and F Block Elements question

2024 · 5 Apr · Shift 2 · Q26
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  5. /2024 · 5 Apr · Shift 2 · Q26

D and F Block Elements question

2024 · 5 Apr · Shift 2 · Q26

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
The fusion of chromite ore with sodium carbonate in the presence of air leads to the formation of products A\mathrm{A}A and B\mathrm{B}B along with the evolution of CO2\mathrm{CO}_2CO2​. The sum of spin-only magnetic moment values of A and B is ‾\underline{\hspace{2cm}}​ B.M. (Nearest integer) [Given atomic number : C:6,Na:11,O:8,Fe:26,Cr:24\mathrm{C}: 6, \mathrm{Na}: 11, \mathrm{O}: 8, \mathrm{Fe}: 26, \mathrm{Cr}: 24C:6,Na:11,O:8,Fe:26,Cr:24]
Numerical answer
View written solutionFree

Correct answer: 6

  1. Identify chromite ore and the fusion reaction

    Chromite ore is FeCr2O4\mathrm{FeCr_2O_4}FeCr2​O4​

    On fusion with sodium carbonate in presence of air, chromite gives sodium chromate and ferric oxide, with evolution of carbon dioxide: 4FeCr2O4+8Na2CO3+7O2→8Na2CrO4+2Fe2O3+8CO24\mathrm{FeCr_2O_4}+8\mathrm{Na_2CO_3}+7\mathrm{O_2}\rightarrow 8\mathrm{Na_2CrO_4}+2\mathrm{Fe_2O_3}+8\mathrm{CO_2}4FeCr2​O4​+8Na2​CO3​+7O2​→8Na2​CrO4​+2Fe2​O3​+8CO2​

    Hence, A=Na2CrO4,B=Fe2O3A=\mathrm{Na_2CrO_4}, \qquad B=\mathrm{Fe_2O_3}A=Na2​CrO4​,B=Fe2​O3​

  2. Find oxidation states and electronic configurations

    For A=Na2CrO4A = \mathrm{Na_2CrO_4}A=Na2​CrO4​

    In chromate ion CrO42−\mathrm{CrO_4^{2-}}CrO42−​, chromium is in oxidation state +6+6+6.

    Neutral Cr: Cr:[Ar]3d54s1\mathrm{Cr}: [Ar]3d^5 4s^1Cr:[Ar]3d54s1

    For Cr6+\mathrm{Cr^{6+}}Cr6+, all 6 valence electrons are removed: Cr6+:3d0\mathrm{Cr^{6+}}: 3d^0Cr6+:3d0

    Number of unpaired electrons n=0n=0n=0.

    Spin-only magnetic moment: μ=n(n+2)=0(0+2)=0 B.M.\mu=\sqrt{n(n+2)}=\sqrt{0(0+2)}=0\ \text{B.M.}μ=n(n+2)​=0(0+2)​=0 B.M.

    For B=Fe2O3B = \mathrm{Fe_2O_3}B=Fe2​O3​

    In Fe2O3\mathrm{Fe_2O_3}Fe2​O3​, iron is in oxidation state +3+3+3.

    Neutral Fe: Fe:[Ar]3d64s2\mathrm{Fe}: [Ar]3d^6 4s^2Fe:[Ar]3d64s2

    So, Fe3+:[Ar]3d5\mathrm{Fe^{3+}}: [Ar]3d^5Fe3+:[Ar]3d5

    In oxide, Fe3+\mathrm{Fe^{3+}}Fe3+ is high spin, so number of unpaired electrons: n=5n=5n=5

    Spin-only magnetic moment: μ=n(n+2)=5(5+2)=35≈5.92 B.M.\mu=\sqrt{n(n+2)}=\sqrt{5(5+2)}=\sqrt{35}\approx 5.92\ \text{B.M.}μ=n(n+2)​=5(5+2)​=35​≈5.92 B.M.

  3. Sum of spin-only magnetic moments of AAA and BBB

    μtotal=0+5.92=5.92 B.M.\mu_{\text{total}}=0+5.92=5.92\ \text{B.M.}μtotal​=0+5.92=5.92 B.M.

    Nearest integer: 6\boxed{6}6​

  4. Comparison with stored answer

    Stored correct answer = 666.

    Our derived answer also = 666.

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