JEE MainChemistryD and F Block ElementsNumerical+4 / −1
In a borax bead test under hot condition, a metal salt (one from the given) is heated at point B of the flame, resulted in green colour salt bead. The spin-only magnetic moment value of the salt is BM (Nearest integer) [Given atomic number of ]Numerical answer
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Correct answer: 6
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Identify the metal ion from borax bead test
In the borax bead test, the colour in the hot flame helps identify the metal ion.
Common hot bead colours:
- : blue-green
- : brown
- : yellow to brown
- : amethyst/violet in oxidising flame, but green bead under hot/reducing condition due to manganate-type species
Since the bead is stated to be green under hot condition, the metal is identified as manganese.
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Determine the relevant electronic configuration
Atomic number of Mn is .
Neutral Mn:
The common salt involved in such tests is typically taken as :
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Count the number of unpaired electrons
For , all five -orbitals are singly occupied:
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Calculate spin-only magnetic moment
Spin-only magnetic moment is:
Substituting :
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Nearest integer
Therefore, the required magnetic moment is BM (nearest integer).
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