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D and F Block Elements question

2024 · 5 Apr · Shift 1 · Q23
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D and F Block Elements question

2024 · 5 Apr · Shift 1 · Q23

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
JEE Main 2024 (Online) 5th April Morning Shift Chemistry - d and f Block Elements Question 27 English In a borax bead test under hot condition, a metal salt (one from the given) is heated at point B of the flame, resulted in green colour salt bead. The spin-only magnetic moment value of the salt is ‾\underline{\hspace{2cm}}​ BM (Nearest integer) [Given atomic number of Cu=29,Ni=28,Mn=25,Fe=26\mathrm{Cu}=29, \mathrm{Ni}=28, \mathrm{Mn}=25, \mathrm{Fe}=26Cu=29,Ni=28,Mn=25,Fe=26]
Numerical answer
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Correct answer: 6

  1. Identify the metal ion from borax bead test

    In the borax bead test, the colour in the hot flame helps identify the metal ion.

    Common hot bead colours:

    • Cu2+\mathrm{Cu^{2+}}Cu2+ : blue-green
    • Ni2+\mathrm{Ni^{2+}}Ni2+ : brown
    • Fe3+\mathrm{Fe^{3+}}Fe3+ : yellow to brown
    • Mn2+\mathrm{Mn^{2+}}Mn2+ : amethyst/violet in oxidising flame, but green bead under hot/reducing condition due to manganate-type species

    Since the bead is stated to be green under hot condition, the metal is identified as manganese.

  2. Determine the relevant electronic configuration

    Atomic number of Mn is 252525.

    Neutral Mn: Mn:[Ar] 3d54s2\mathrm{Mn} : [Ar] \, 3d^5 4s^2Mn:[Ar]3d54s2

    The common salt involved in such tests is typically taken as Mn2+\mathrm{Mn^{2+}}Mn2+: Mn2+:[Ar] 3d5\mathrm{Mn^{2+}} : [Ar] \, 3d^5Mn2+:[Ar]3d5

  3. Count the number of unpaired electrons

    For 3d53d^53d5, all five ddd-orbitals are singly occupied: n=5n = 5n=5

  4. Calculate spin-only magnetic moment

    Spin-only magnetic moment is: μ=n(n+2) BM\mu = \sqrt{n(n+2)} \text{ BM}μ=n(n+2)​ BM

    Substituting n=5n=5n=5: μ=5(5+2)=35≈5.92 BM\mu = \sqrt{5(5+2)} = \sqrt{35} \approx 5.92 \text{ BM}μ=5(5+2)​=35​≈5.92 BM

  5. Nearest integer

    5.92≈65.92 \approx 65.92≈6

Therefore, the required magnetic moment is 666 BM (nearest integer).

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