Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

D and F Block Elements question

2022 · 28 Jun · Shift 1 · Q3
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /D and F Block Elements
  5. /2022 · 28 Jun · Shift 1 · Q3

D and F Block Elements question

2022 · 28 Jun · Shift 1 · Q3

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Which one of the lanthanoids given below is the most stable in divalent form?
  1. A
    Ce (Atomic Number 58)
  2. B
    Sm (Atomic number 62)
  3. C
    Eu (Atomic Number 63)
  4. D
    Yb (Atomic Number 70)
View written solutionFree

Correct answer: C

  1. Key idea: For lanthanoids, the divalent state Ln2+\text{Ln}^{2+}Ln2+ is especially stable when it gives a particularly stable 4f4f4f electronic configuration such as:

    • half-filled: 4f74f^74f7
    • fully filled: 4f144f^{14}4f14
  2. Check the electronic configurations of the given lanthanoids:

    • Ce (Z=58Z=58Z=58): Ce=[Xe]4f15d16s2\text{Ce} = [Xe]4f^15d^16s^2Ce=[Xe]4f15d16s2 Ce2+≈[Xe]4f25d0\text{Ce}^{2+} \approx [Xe]4f^25d^0Ce2+≈[Xe]4f25d0 This is not especially stable.

    • Sm (Z=62Z=62Z=62): Sm=[Xe]4f66s2\text{Sm} = [Xe]4f^66s^2Sm=[Xe]4f66s2 Sm2+=[Xe]4f6\text{Sm}^{2+} = [Xe]4f^6Sm2+=[Xe]4f6 This is somewhat stable, but not half-filled or fully filled.

    • Eu (Z=63Z=63Z=63): Eu=[Xe]4f76s2\text{Eu} = [Xe]4f^76s^2Eu=[Xe]4f76s2 Eu2+=[Xe]4f7\text{Eu}^{2+} = [Xe]4f^7Eu2+=[Xe]4f7 This gives a half-filled 4f74f^74f7 configuration, which is highly stable.

    • Yb (Z=70Z=70Z=70): Yb=[Xe]4f146s2\text{Yb} = [Xe]4f^{14}6s^2Yb=[Xe]4f146s2 Yb2+=[Xe]4f14\text{Yb}^{2+} = [Xe]4f^{14}Yb2+=[Xe]4f14 This gives a fully filled 4f144f^{14}4f14 configuration, also highly stable.

  3. Compare Eu2+^{2+}2+ and Yb2+^{2+}2+: Both are unusually stable in the divalent state. However, in standard JEE chemistry, Eu2+^{2+}2+ is regarded as the most stable/common divalent lanthanoid because of the exceptional stability of the half-filled 4f74f^74f7 configuration.

  4. Evaluate options:

    • A: Ce — incorrect
    • B: Sm — incorrect
    • C: Eu — correct
    • D: Yb — very stable, but not the best answer here
  5. Final answer: Eu (Option C)\boxed{\text{Eu (Option C)}}Eu (Option C)​

  6. Comparison with stored correct answer: Stored answer is C, which matches the derived answer.

PreviousNext

More from D and F Block Elements

  • The reaction of zinc with excess of aqueous alkali, evolves hydrogen gas and gives :2022 · MCQ
  • In following pairs, the one in which both transition metal ions are colourless is :2022 · MCQ
  • In neutral or faintly alkaline medium, KMnO4​ being a powerful oxidant can oxidize, thiosulphate almost quantitatively, to sulphate. In this reaction overall change in oxidation state of manganese will be :2022 · MCQ
  • Which of the following 3d-metal ion will give the lowest enthalpy of hydration (Δhyd ​H) when dissolved in water ?2022 · MCQ
  • The number of terminal oxygen atoms present in the product B obtained from the following reaction is ​. FeCr2​O4​ + Na2​CO3​ + O2​ → A + Fe2​O3​ + CO2​ A + H+→ B + H2​O + Na+2022 · Numerical
  • An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in higher oxidation state is ​ B.M. (Nearest integer)2022 · Numerical
  • The electronic configuration of Pt (atomic number 78) is :2022 · MCQ
  • Spin only magnetic moment of [MnBr6​]4− is ​ B.M. (round off to the closest integer)2022 · Numerical