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D and F Block Elements question

2021 · 24 Feb · Shift 2 · Q2
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D and F Block Elements question

2021 · 24 Feb · Shift 2 · Q2

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The incorrect statement among the following is :
  1. A
    RuO4RuO_4RuO4​ is an oxidizing agent
  2. B
    Cr2O3Cr_2O_3Cr2​O3​ is an amphoteric oxide.
  3. C
    VOSO4VOSO_4VOSO4​ is a reducing agent
  4. D
    Red colour of ruby is due to the presence of Co3+Co^{3+}Co3+
View written solutionFree

Correct answer: D

  1. We check each statement one by one.

  2. Option A: RuO4RuO_4RuO4​ is an oxidizing agent.

    • Ruthenium tetroxide, RuO4RuO_4RuO4​, is analogous to OsO4OsO_4OsO4​ and contains Ru in a very high oxidation state, +8+8+8.
    • Species in very high oxidation states generally act as strong oxidizing agents.
    • Therefore, this statement is correct.
  3. Option B: Cr2O3Cr_2O_3Cr2​O3​ is an amphoteric oxide.

    • Cr2O3Cr_2O_3Cr2​O3​ reacts with both acids and bases.
    • With acids, it behaves as a basic oxide: Cr2O3+6H+→2Cr3++3H2OCr_2O_3 + 6H^+ \rightarrow 2Cr^{3+} + 3H_2OCr2​O3​+6H+→2Cr3++3H2​O
    • With strong bases, it shows acidic character and forms chromite-type species.
    • Hence, Cr2O3Cr_2O_3Cr2​O3​ is amphoteric.
    • So this statement is correct.
  4. Option C: VOSO4VOSO_4VOSO4​ is a reducing agent.

    • In VOSO4VOSO_4VOSO4​, vanadium is present as vanadyl ion, VO2+VO^{2+}VO2+.
    • Oxidation state of V: x+(−2)=+2⇒x=+4x + (-2) = +2 \Rightarrow x = +4x+(−2)=+2⇒x=+4
    • Thus vanadium is in the +4+4+4 state.
    • Since vanadium can be oxidized from +4+4+4 to +5+5+5, VOSO4VOSO_4VOSO4​ tends to act as a reducing agent.
    • Therefore, this statement is correct.
  5. Option D: Red colour of ruby is due to the presence of Co3+Co^{3+}Co3+.

    • Ruby is essentially Al2O3Al_2O_3Al2​O3​ containing traces of Cr3+Cr^{3+}Cr3+ impurity.
    • The red colour of ruby is due to Cr3+Cr^{3+}Cr3+, not Co3+Co^{3+}Co3+.
    • Therefore, this statement is incorrect.
  6. Since the question asks for the incorrect statement, the answer is: D\boxed{D}D​

  7. Comparison with stored correct answer:

    • Stored correct answer: DDD
    • Derived answer: DDD
    • They match.
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