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D and F Block Elements question

2019 · 11 Jan · Shift 1 · Q6
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D and F Block Elements question

2019 · 11 Jan · Shift 1 · Q6

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The element that usually does NOT show variable oxidation states is :
  1. A
    V
  2. B
    Cu
  3. C
    Sc
  4. D
    ti
View written solutionFree

Correct answer: C

  1. Concept used

    Variable oxidation state is a common property of transition elements because both nsnsns and (n−1)d(n-1)d(n−1)d electrons can participate in bonding.

    However, some elements show only one common oxidation state because they attain a particularly stable configuration.

  2. Check each option

    A: Vanadium (V)(\mathrm{V})(V)

    Vanadium shows several oxidation states: +2,+3,+4,+5+2, +3, +4, +5+2,+3,+4,+5 So, it does show variable oxidation states.

    B: Copper (Cu)(\mathrm{Cu})(Cu)

    Copper commonly shows: +1,+2+1, +2+1,+2 Hence, it does show variable oxidation states.

    C: Scandium (Sc)(\mathrm{Sc})(Sc)

    Scandium has electronic configuration: [Ar] 3d14s2[\mathrm{Ar}]\,3d^1 4s^2[Ar]3d14s2 It most commonly forms: Sc3+:[Ar]\mathrm{Sc}^{3+} : [\mathrm{Ar}]Sc3+:[Ar] This noble gas configuration is very stable, so scandium usually shows only the +3+3+3 oxidation state.

    Therefore, scandium usually does NOT show variable oxidation states.

    D: Titanium (Ti)(\mathrm{Ti})(Ti)

    Titanium shows multiple oxidation states such as: +2,+3,+4+2, +3, +4+2,+3,+4 So, it does show variable oxidation states.

  3. Conclusion

    The element that usually does not show variable oxidation states is: Sc\boxed{\mathrm{Sc}}Sc​

  4. Compare with stored answer

    Stored correct answer: C

    Derived answer: C

    So the derived answer agrees with the stored answer.

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