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D and F Block Elements question

2019 · 12 Jan · Shift 2 · Q5
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  5. /2019 · 12 Jan · Shift 2 · Q5

D and F Block Elements question

2019 · 12 Jan · Shift 2 · Q5

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The correct order of atomic radii is :
  1. A
    Ho > N > Eu > Ce
  2. B
    Ce > Eu > Ho > N
  3. C
    N > Ce > Eu > Ho
  4. D
    Eu > Ce > Ho > N
View written solutionFree

Correct answer: CORRECT ORDER: EU > CE > ND > HO, STORED OPTION D IS INCORRECT BECAUSE IT PLACES HO > ND

  1. Identify the elements involved

The symbols are:

  • Ce\mathrm{Ce}Ce = Cerium
  • Eu\mathrm{Eu}Eu = Europium
  • Ho\mathrm{Ho}Ho = Holmium
  • N\mathrm{N}N = Neodymium

All are lanthanoids.

  1. Recall the trend in atomic radii across lanthanoids

Across the lanthanoid series, atomic radii decrease gradually from left to right due to lanthanoid contraction.

So in general: earlier lanthanoid>later lanthanoid\text{earlier lanthanoid} > \text{later lanthanoid}earlier lanthanoid>later lanthanoid

Their positions are:

  • Ce\mathrm{Ce}Ce : early
  • N\mathrm{N}N (Nd) : after Ce
  • Eu\mathrm{Eu}Eu : after Nd
  • Ho\mathrm{Ho}Ho : much later

Thus, expected trend from periodic position is: Ce>Nd>Eu>Ho\mathrm{Ce} > \mathrm{Nd} > \mathrm{Eu} > \mathrm{Ho}Ce>Nd>Eu>Ho

  1. Use the known exception / actual atomic radii values

Among lanthanoids, there are small irregularities due to electronic configuration. Europium has a relatively larger atomic radius than expected because of its stable half-filled 4f74f^74f7 configuration.

Hence the actual order becomes: Eu>Ce>Nd>Ho\mathrm{Eu} > \mathrm{Ce} > \mathrm{Nd} > \mathrm{Ho}Eu>Ce>Nd>Ho

  1. Match with the options

Option D says: Eu>Ce>Ho>N\mathrm{Eu} > \mathrm{Ce} > \mathrm{Ho} > \mathrm{N}Eu>Ce>Ho>N This places Ho>Nd\mathrm{Ho} > \mathrm{Nd}Ho>Nd, which is incorrect because due to lanthanoid contraction, Nd\mathrm{Nd}Nd must be larger than Ho\mathrm{Ho}Ho.

Option C says: N>Ce>Eu>Ho\mathrm{N} > \mathrm{Ce} > \mathrm{Eu} > \mathrm{Ho}N>Ce>Eu>Ho This wrongly places Nd>Ce\mathrm{Nd} > \mathrm{Ce}Nd>Ce and Ce>Eu\mathrm{Ce} > \mathrm{Eu}Ce>Eu.

Option B says: Ce>Eu>Ho>N\mathrm{Ce} > \mathrm{Eu} > \mathrm{Ho} > \mathrm{N}Ce>Eu>Ho>N This again wrongly places Ho>Nd\mathrm{Ho} > \mathrm{Nd}Ho>Nd.

Option A says: Ho>N>Eu>Ce\mathrm{Ho} > \mathrm{N} > \mathrm{Eu} > \mathrm{Ce}Ho>N>Eu>Ce Clearly incorrect.

  1. Conclusion

The correct order should be: Eu>Ce>Nd>Ho\boxed{\mathrm{Eu} > \mathrm{Ce} > \mathrm{Nd} > \mathrm{Ho}}Eu>Ce>Nd>Ho​

But this exact order is not present in the options.

So the stored answer D\mathrm{D}D is not correct, because Nd\mathrm{Nd}Nd should be larger than Ho\mathrm{Ho}Ho.

Therefore, the question/options likely contain a mistake.

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