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D and F Block Elements question

2019 · 10 Jan · Shift 2 · Q19
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D and F Block Elements question

2019 · 10 Jan · Shift 2 · Q19

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The 71st electron of an element X with an atomic number of 71 enters into the orbital :
  1. A
    4f
  2. B
    6s
  3. C
    6p
  4. D
    5d
View written solutionFree

Correct answer: D

  1. Identify the element

    The atomic number is 717171, so the element has 717171 electrons in the neutral state.

  2. Write the electronic configuration up to this point

    Using the Aufbau principle, the filling sequence around this region is: 6s→4f→5d6s \rightarrow 4f \rightarrow 5d6s→4f→5d

    Up to atomic number 707070 (ytterbium), the configuration is: [Xe]4f146s2[Xe]4f^{14}6s^2[Xe]4f146s2

  3. Add the 71st electron

    The next electron, i.e. the 71st71^{\text{st}}71st electron, enters the 5d5d5d orbital.

    So for atomic number 717171 (lutetium), the configuration is: [Xe]4f145d16s2[Xe]4f^{14}5d^16s^2[Xe]4f145d16s2

  4. Check the options

    • A: 4f4f4f ❌
    • B: 6s6s6s ❌
    • C: 6p6p6p ❌
    • D: 5d5d5d ✅

Therefore, the 71st71^{\text{st}}71st electron enters the 5d5d5d orbital.

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