JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The incorrect statement is :
- Asalts give red coloured borax bead test in reducing flame.
- Band ions give black precipitate with in presence of solution.
- CFerric ion gives blood red color with potasium thiocyanate.
- Dion gives chocolate coloured preciitate with potassium ferrocyanide solution.
View written solutionFree
Correct answer: B
-
Check option A: Borax bead test for copper
In the borax bead test, copper salts give:
- blue-green bead in oxidising flame
- red/opaque bead in reducing flame due to formation of metallic copper or cuprous oxide.
So statement A is correct.
-
Check option B: Reaction of and with in presence of
In qualitative analysis:
- In acidic medium ( present), only group II cations precipitate with because sulfide ion concentration is low.
- belongs to group II and gives black precipitate of .
- belongs to group IV, and it does not precipitate with in acidic medium. It precipitates as only in alkaline medium.
Therefore the statement that both and give black precipitate with in presence of is incorrect.
-
Check option C: Ferric ion with potassium thiocyanate
gives a blood-red complex with thiocyanate ion:
Hence statement C is correct.
-
Check option D: with potassium ferrocyanide
reacts with potassium ferrocyanide, , to give a chocolate-brown precipitate of copper ferrocyanide.
Therefore statement D is correct.
-
Conclusion
The only incorrect statement is:
More from D and F Block Elements
- The pair of compounds having metals in their highest oxidation state is :2017 · MCQ
- Which of the following ions does not liberate hydrogen gas on reaction with dilute acids ?2017 · MCQ
- In the following reactions, is respectively acting as a/an : (a) + (b) + 2017 · MCQ
- Which one of the following species is stable in aqueous solution?2016 · MCQ
- The transition metal ions responsible for color in ruby and emerald are, respectively :2016 · MCQ
- Which of the following compounds is metallic and ferromagnetic ?2016 · MCQ
- The reaction of zinc with dilute and concentrated nitric acid, respectively, produces :2016 · MCQ
- The colour of is due to :2015 · MCQ