JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The INCORRECT statement is :
- Athe color of is violet as it absorbs the yellow light.
- Bthe gemstone, ruby, has ions occupying the octahedral sites of beryl.
- Cthe spin-only magnetic moment of is 2.83 BM.
- Dthe spin-only magnetic moments of and are nearly similar.
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Correct answer: B
- We check each statement one by one.
- Option A: is violet as it absorbs yellow light.
- The observed color of a complex is complementary to the color absorbed.
- Yellow light and violet color are complementary.
- Hence, if the complex absorbs yellow light, it can appear violet.
So, Option A is correct.
- Option B: the gemstone, ruby, has ions occupying the octahedral sites of beryl.
- Ruby is not beryl.
- Ruby is a variety of corundum, which is .
- Its red color is due to trace amounts of replacing in the crystal lattice.
- Beryl is a different mineral: .
Therefore this statement is incorrect.
- Option C: the spin-only magnetic moment of is .
- For , electronic configuration is .
- In an octahedral complex with and , the configuration remains with 2 unpaired electrons.
- Spin-only magnetic moment: where = number of unpaired electrons.
- Here :
So, Option C is correct.
- Option D: the spin-only magnetic moments of and are nearly similar.
Let us calculate both.
For
- is .
- is a weak-field ligand, so this is high spin octahedral.
- Number of unpaired electrons .
- Magnetic moment:
For
- is .
- With weak-field ligand , this is high spin octahedral.
- Number of unpaired electrons .
- Magnetic moment:
Thus, the two magnetic moments are indeed nearly the same.
So, Option D is correct.
- Hence, the only incorrect statement is:
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