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D and F Block Elements question

2019 · 10 Apr · Shift 2 · Q16
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D and F Block Elements question

2019 · 10 Apr · Shift 2 · Q16

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The INCORRECT statement is :
  1. A
    the color of [CoCl(NH3)5]2+[CoCl(NH_3)_5]^{2+}[CoCl(NH3​)5​]2+ is violet as it absorbs the yellow light.
  2. B
    the gemstone, ruby, has Cr3+Cr^{3+}Cr3+ ions occupying the octahedral sites of beryl.
  3. C
    the spin-only magnetic moment of [Ni(NH3)4(H2O)2]2+[Ni(NH_3)_4(H_2O)_2]^{2+}[Ni(NH3​)4​(H2​O)2​]2+ is 2.83 BM.
  4. D
    the spin-only magnetic moments of [Fe(H2O)6]2+[Fe(H_2O)_6]^{2+}[Fe(H2​O)6​]2+ and [Cr(H2O)6]2+[Cr(H_2O)_6]^{2+}[Cr(H2​O)6​]2+ are nearly similar.
View written solutionFree

Correct answer: B

  1. We check each statement one by one.

  1. Option A: [CoCl(NH3)5]2+[CoCl(NH_3)_5]^{2+}[CoCl(NH3​)5​]2+ is violet as it absorbs yellow light.
  • The observed color of a complex is complementary to the color absorbed.
  • Yellow light and violet color are complementary.
  • Hence, if the complex absorbs yellow light, it can appear violet.

So, Option A is correct.


  1. Option B: the gemstone, ruby, has Cr3+Cr^{3+}Cr3+ ions occupying the octahedral sites of beryl.
  • Ruby is not beryl.
  • Ruby is a variety of corundum, which is Al2O3Al_2O_3Al2​O3​.
  • Its red color is due to trace amounts of Cr3+Cr^{3+}Cr3+ replacing Al3+Al^{3+}Al3+ in the crystal lattice.
  • Beryl is a different mineral: Be3Al2Si6O18Be_3Al_2Si_6O_{18}Be3​Al2​Si6​O18​.

Therefore this statement is incorrect.


  1. Option C: the spin-only magnetic moment of [Ni(NH3)4(H2O)2]2+[Ni(NH_3)_4(H_2O)_2]^{2+}[Ni(NH3​)4​(H2​O)2​]2+ is 2.83 BM2.83\,\text{BM}2.83BM.
  • For Ni2+Ni^{2+}Ni2+, electronic configuration is 3d83d^83d8.
  • In an octahedral complex with NH3NH_3NH3​ and H2OH_2OH2​O, the configuration remains with 2 unpaired electrons.
  • Spin-only magnetic moment: μ=n(n+2)\mu = \sqrt{n(n+2)}μ=n(n+2)​ where nnn = number of unpaired electrons.
  • Here n=2n=2n=2: μ=2(2+2)=8=2.83 BM\mu = \sqrt{2(2+2)} = \sqrt{8} = 2.83\,\text{BM}μ=2(2+2)​=8​=2.83BM

So, Option C is correct.


  1. Option D: the spin-only magnetic moments of [Fe(H2O)6]2+[Fe(H_2O)_6]^{2+}[Fe(H2​O)6​]2+ and [Cr(H2O)6]2+[Cr(H_2O)_6]^{2+}[Cr(H2​O)6​]2+ are nearly similar.

Let us calculate both.

For [Fe(H2O)6]2+[Fe(H_2O)_6]^{2+}[Fe(H2​O)6​]2+

  • Fe2+Fe^{2+}Fe2+ is 3d63d^63d6.
  • H2OH_2OH2​O is a weak-field ligand, so this is high spin octahedral.
  • Number of unpaired electrons n=4n=4n=4.
  • Magnetic moment: μ=4(4+2)=24≈4.90 BM\mu = \sqrt{4(4+2)} = \sqrt{24} \approx 4.90\,\text{BM}μ=4(4+2)​=24​≈4.90BM

For [Cr(H2O)6]2+[Cr(H_2O)_6]^{2+}[Cr(H2​O)6​]2+

  • Cr2+Cr^{2+}Cr2+ is 3d43d^43d4.
  • With weak-field ligand H2OH_2OH2​O, this is high spin octahedral.
  • Number of unpaired electrons n=4n=4n=4.
  • Magnetic moment: μ=4(4+2)=24≈4.90 BM\mu = \sqrt{4(4+2)} = \sqrt{24} \approx 4.90\,\text{BM}μ=4(4+2)​=24​≈4.90BM

Thus, the two magnetic moments are indeed nearly the same.

So, Option D is correct.


  1. Hence, the only incorrect statement is:

B\boxed{\text{B}}B​

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