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D and F Block Elements question

2019 · 10 Jan · Shift 1 · Q16
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D and F Block Elements question

2019 · 10 Jan · Shift 1 · Q16

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The effect of lanthanoid contraction in the lanthanoid series of elements by and large means :
  1. A
    increase in atomic radii and decrease in ionic radii
  2. B
    increase in both atomic and ionic radii
  3. C
    decrease in both atomic and ionic radii
  4. D
    decrease in atomic radii and increase in ionic radii
View written solutionFree

Correct answer: C

  1. Meaning of lanthanoid contraction

    As we move across the lanthanoid series from La to Lu, electrons are added to the 4f4f4f-subshell.

  2. Cause of contraction

    The 4f4f4f electrons shield the nuclear charge very poorly. Therefore, the effective nuclear charge on the outer electrons increases steadily.

  3. Effect on size

    Because of the increasing effective nuclear charge, the electrons are pulled closer to the nucleus.

    Hence, across the lanthanoid series:

    • atomic radii decrease
    • ionic radii also decrease
  4. Evaluation of options

    • A: increase in atomic radii and decrease in ionic radii →\rightarrow→ incorrect
    • B: increase in both atomic and ionic radii →\rightarrow→ incorrect
    • C: decrease in both atomic and ionic radii →\rightarrow→ correct
    • D: decrease in atomic radii and increase in ionic radii →\rightarrow→ incorrect
  5. Final answer

    The lanthanoid contraction means a gradual decrease in both atomic and ionic radii across the series.

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