JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The effect of lanthanoid contraction in the lanthanoid series of elements by and large means :
- Aincrease in atomic radii and decrease in ionic radii
- Bincrease in both atomic and ionic radii
- Cdecrease in both atomic and ionic radii
- Ddecrease in atomic radii and increase in ionic radii
View written solutionFree
Correct answer: C
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Meaning of lanthanoid contraction
As we move across the lanthanoid series from La to Lu, electrons are added to the -subshell.
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Cause of contraction
The electrons shield the nuclear charge very poorly. Therefore, the effective nuclear charge on the outer electrons increases steadily.
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Effect on size
Because of the increasing effective nuclear charge, the electrons are pulled closer to the nucleus.
Hence, across the lanthanoid series:
- atomic radii decrease
- ionic radii also decrease
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Evaluation of options
- A: increase in atomic radii and decrease in ionic radii incorrect
- B: increase in both atomic and ionic radii incorrect
- C: decrease in both atomic and ionic radii correct
- D: decrease in atomic radii and increase in ionic radii incorrect
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Final answer
The lanthanoid contraction means a gradual decrease in both atomic and ionic radii across the series.
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