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D and F Block Elements question

2011 · Shift 0 · Q19
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D and F Block Elements question

2011 · Shift 0 · Q19

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
In context of the lanthanoids, which of the following statements is not correct?
  1. A
    All the members exhibit +3 oxidation state
  2. B
    Because of similar properties the separation of lanthanoids is not easy.
  3. C
    Availability of 4f electrons results in the formation of compounds in +4 state for all the members of the series.
  4. D
    There is a gradual decrease in the radii of the members with increasing atomic number in the series.
View written solutionFree

Correct answer: C

  1. Understand the question

We need to identify the statement about lanthanoids that is not correct.

  1. Check each option

Option A: All the members exhibit +3+3+3 oxidation state

Lanthanoids most commonly show the +3+3+3 oxidation state.

This is a characteristic oxidation state of the lanthanoids, so this statement is taken as correct.

Option B: Because of similar properties the separation of lanthanoids is not easy.

Lanthanoids have very similar ionic sizes and usually show the same oxidation state (+3)(+3)(+3), so their chemical properties are very similar.

Hence, their separation is indeed difficult. So this statement is correct.

Option C: Availability of 4f4f4f electrons results in the formation of compounds in +4+4+4 state for all the members of the series.

This is incorrect.

Only some lanthanoids show the +4+4+4 oxidation state, such as:

  • Ce4+Ce^{4+}Ce4+
  • Pr4+Pr^{4+}Pr4+ (rare)
  • Tb4+Tb^{4+}Tb4+

It is not shown by all lanthanoids.

So this statement is not correct.

Option D: There is a gradual decrease in the radii of the members with increasing atomic number in the series.

This is the phenomenon of lanthanoid contraction.

As atomic number increases, the size decreases gradually due to poor shielding by 4f4f4f electrons.

So this statement is correct.

  1. Conclusion

The incorrect statement is:

C\boxed{C}C​

  1. Comparison with stored correct answer

Stored correct answer = CCC

My derived answer also = CCC

So they agree.

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