- Ais more ionic than
- Bis more easily hydrolysed than
- Cis more volatile than
- Dis more soluble in anhydrous ethanol than .
View written solutionFree
Correct answer: A
- Identify the comparison
A metal forms two chlorides:
- where metal is in oxidation state
- where metal is in oxidation state
We must compare their properties.
- Use Fajans' rule / polarization concept
A cation with:
- higher positive charge,
- smaller size,
has greater polarising power and hence produces more covalent character in its compounds.
So, compared to , the ion has much higher polarising power.
Therefore:
So option A is correct.
- Check the remaining options
Option B: is more easily hydrolysed than
More covalent chlorides are generally more easily hydrolysed.
Since is more covalent than , we expect: Hence B is false.
Option C: is more volatile than
More covalent compounds are generally more volatile, while ionic compounds are less volatile.
Since is more covalent, it is expected to be more volatile. Thus C is false.
Option D: is more soluble in anhydrous ethanol than
Covalent compounds tend to dissolve better in organic solvents such as anhydrous ethanol, while ionic compounds prefer polar solvents like water.
Since is more covalent, it should be more soluble in anhydrous ethanol. Thus D is false.
- Final conclusion
The correct statement is:
- Comparison with stored correct answer
Stored correct answer: A
Derived answer: A
They match.
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