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D and F Block Elements question

2006 · Shift 0 · Q27
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D and F Block Elements question

2006 · Shift 0 · Q27

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
A metal, MMM forms chlorides in its +2+2+2 and +4+4+4 oxidation states. Which of the following statements about these chlorides is correct?
  1. A
    MCl2MC{l_2}MCl2​ is more ionic than MCl4MC{l_4}MCl4​
  2. B
    MCl2MC{l_2}MCl2​ is more easily hydrolysed than MCl4MC{l_4}MCl4​
  3. C
    MCl2MC{l_2}MCl2​ is more volatile than MCl4MC{l_4}MCl4​
  4. D
    MCl2MC{l_2}MCl2​ is more soluble in anhydrous ethanol than MCl4MC{l_4}MCl4​.
View written solutionFree

Correct answer: A

  1. Identify the comparison

A metal MMM forms two chlorides:

  • MCl2MCl_2MCl2​ where metal is in +2+2+2 oxidation state
  • MCl4MCl_4MCl4​ where metal is in +4+4+4 oxidation state

We must compare their properties.

  1. Use Fajans' rule / polarization concept

A cation with:

  • higher positive charge,
  • smaller size,

has greater polarising power and hence produces more covalent character in its compounds.

So, compared to M2+M^{2+}M2+, the ion M4+M^{4+}M4+ has much higher polarising power.

Therefore: MCl4 is more covalent, while MCl2 is more ionic.MCl_4 \text{ is more covalent, while } MCl_2 \text{ is more ionic.}MCl4​ is more covalent, while MCl2​ is more ionic.

So option A is correct.

  1. Check the remaining options

Option B: MCl2MCl_2MCl2​ is more easily hydrolysed than MCl4MCl_4MCl4​

More covalent chlorides are generally more easily hydrolysed.

Since MCl4MCl_4MCl4​ is more covalent than MCl2MCl_2MCl2​, we expect: MCl4 is more easily hydrolysed than MCl2MCl_4 \text{ is more easily hydrolysed than } MCl_2MCl4​ is more easily hydrolysed than MCl2​ Hence B is false.

Option C: MCl2MCl_2MCl2​ is more volatile than MCl4MCl_4MCl4​

More covalent compounds are generally more volatile, while ionic compounds are less volatile.

Since MCl4MCl_4MCl4​ is more covalent, it is expected to be more volatile. Thus C is false.

Option D: MCl2MCl_2MCl2​ is more soluble in anhydrous ethanol than MCl4MCl_4MCl4​

Covalent compounds tend to dissolve better in organic solvents such as anhydrous ethanol, while ionic compounds prefer polar solvents like water.

Since MCl4MCl_4MCl4​ is more covalent, it should be more soluble in anhydrous ethanol. Thus D is false.

  1. Final conclusion

The correct statement is: A: MCl2 is more ionic than MCl4\boxed{\text{A: } MCl_2 \text{ is more ionic than } MCl_4}A: MCl2​ is more ionic than MCl4​​

  1. Comparison with stored correct answer

Stored correct answer: A

Derived answer: A

They match.

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