- Agets oxidised by oxalic acid to chlorine
- Bfurnishes ions in addition to those from oxalic acid
- Creduces permanganate to
- Doxaidises oxalic acid to carbon doxide and water
View written solutionFree
Correct answer: C
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What happens in the titration?
In acidic medium, potassium permanganate oxidizes oxalic acid.
The relevant reaction is:
So, the titration must be carried out in an acidic medium, and usually dilute is used.
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Why is not used?
Permanganate is a strong oxidizing agent in acidic medium. In presence of , the chloride ion gets oxidized to chlorine gas.
The reaction is:
Thus, also reacts with , consuming permanganate and disturbing the titration result.
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Check the options
A. gets oxidised by oxalic acid to chlorine
Incorrect. Oxalic acid is a reducing agent; it does not oxidize to chlorine.B. furnishes ions in addition to those from oxalic acid
Incorrect. Acidic medium is required anyway; this is not the reason for unsatisfactory results.C. reduces permanganate to
This is the closest correct statement in the given options. More precisely, chloride ion from gets oxidized, thereby reducing permanganate to and causing error.D. oxidises oxalic acid to carbon dioxide and water
Incorrect. is not an oxidizing agent here. -
Conclusion
The titration gives unsatisfactory results in presence of because (through ) reacts with permanganate, reducing to .
Therefore, the correct option is:
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