JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Identify the incorrect statement among the following :
- Ad-Block elements show irregular and erratic chemical properties among themselves
- BLa and Lu have partially filled d orbitals and no other partially filled orbitals
- CThe chemistry of various lanthanoids is very similar
- D4f and 5f orbitals are equally shielded
View written solutionFree
Correct answer: D
- Check each statement one by one.
- Option A: d-Block elements show irregular and erratic chemical properties among themselves
This is true.
Reason:
- In the -block, electrons are added to the penultimate -subshell.
- Because of small differences in energies of and orbitals, these elements show:
- variable oxidation states,
- irregular trends in atomic size,
- magnetic behavior,
- catalytic properties.
So, chemical properties are indeed somewhat irregular and erratic across the series.
- Option B: La and Lu have partially filled d orbitals and no other partially filled orbitals
This is true.
Electronic configurations:
In both cases:
- the orbital is partially filled (),
- there is no other partially filled subshell.
Hence this statement is correct.
- Option C: The chemistry of various lanthanoids is very similar
This is true.
Reason:
- Lanthanoids mainly show the oxidation state .
- The differentiating electrons enter the inner orbitals.
- Since electrons do not participate much in bonding, their chemical properties remain very similar.
So this statement is also correct.
- Option D: 4f and 5f orbitals are equally shielded
This is incorrect.
Reason:
- orbitals are poorly shielded.
- orbitals are also shielded poorly, but they are less deeply buried and participate more in bonding than orbitals.
- Hence, and orbitals are not equally shielded.
This difference is one reason actinoids show more variable oxidation states compared to lanthanoids.
- Conclusion
The incorrect statement is:
More from D and F Block Elements
- A metal, forms chlorides in its and oxidation states. Which of the following statements about these chlorides is correct?2006 · MCQ
- The “spin-only” magnetic moment [in units of Bohr magneton, (µB)] of in aqueous solution would be : (Atomic number of Ni = 28)2006 · MCQ
- Lanthanoid contraction is caused due to :2006 · MCQ
- The oxidation state of chromium in the final product formed the reaction between and acidified potassium dichromate solution is :2005 · MCQ
- On heating mixture of and will give :2005 · MCQ
- Calomel on reaction with ammonium hydroxide gives :2005 · MCQ
- The lanthanide contraction is responsible for the fact that :2005 · MCQ
- Which of the following factors may be regarded as the main cause of lanthanide contraction?2005 · MCQ