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D and F Block Elements question

2008 · Shift 0 · Q20
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D and F Block Elements question

2008 · Shift 0 · Q20

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Larger number of oxidation states are exhibited by the actinoids than those by the lanthanoids, the main reason being :
  1. A
    4f orbitals more diffused than the 5f orbitals
  2. B
    lesser energy difference between 5f and 6d than between 4f and 5d orbitals
  3. C
    more energy difference between 5f and 6d than between 4f and 5d orbitals
  4. D
    more reactive nature of the actinoids than the lanthanoids
View written solutionFree

Correct answer: B

  1. Concept involved

    The number of oxidation states shown by an element depends on how many electrons can participate in bonding.

    • Lanthanoids: involve mainly 4f4f4f, 5d5d5d, and 6s6s6s electrons.
    • Actinoids: involve mainly 5f5f5f, 6d6d6d, and 7s7s7s electrons.
  2. Key difference between lanthanoids and actinoids

    In lanthanoids, the energy gap between 4f4f4f and 5d5d5d orbitals is comparatively larger, so fewer electrons are available for variable bonding.

    In actinoids, the energies of 5f5f5f and 6d6d6d orbitals are very close. Because of this small energy difference, electrons from both 5f5f5f and 6d6d6d orbitals can participate in bonding.

    Hence, actinoids exhibit a larger number of oxidation states.

  3. Evaluation of options

    A: 4f4f4f orbitals more diffused than 5f5f5f orbitals
    This is false. In fact, 5f5f5f orbitals are less effectively shielded and can participate more in bonding than 4f4f4f in early actinoids. So this is not the reason.

    B: lesser energy difference between 5f5f5f and 6d6d6d than between 4f4f4f and 5d5d5d orbitals
    This is correct. This directly explains why actinoids show more oxidation states.

    C: more energy difference between 5f5f5f and 6d6d6d than between 4f4f4f and 5d5d5d orbitals
    Opposite of the correct reason, so false.

    D: more reactive nature of the actinoids than the lanthanoids
    Reactivity alone is not the main reason for larger number of oxidation states.

  4. Final answer

    Therefore, the correct option is: B\boxed{\text{B}}B​

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