- A4f orbitals more diffused than the 5f orbitals
- Blesser energy difference between 5f and 6d than between 4f and 5d orbitals
- Cmore energy difference between 5f and 6d than between 4f and 5d orbitals
- Dmore reactive nature of the actinoids than the lanthanoids
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Correct answer: B
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Concept involved
The number of oxidation states shown by an element depends on how many electrons can participate in bonding.
- Lanthanoids: involve mainly , , and electrons.
- Actinoids: involve mainly , , and electrons.
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Key difference between lanthanoids and actinoids
In lanthanoids, the energy gap between and orbitals is comparatively larger, so fewer electrons are available for variable bonding.
In actinoids, the energies of and orbitals are very close. Because of this small energy difference, electrons from both and orbitals can participate in bonding.
Hence, actinoids exhibit a larger number of oxidation states.
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Evaluation of options
A: orbitals more diffused than orbitals
This is false. In fact, orbitals are less effectively shielded and can participate more in bonding than in early actinoids. So this is not the reason.B: lesser energy difference between and than between and orbitals
This is correct. This directly explains why actinoids show more oxidation states.C: more energy difference between and than between and orbitals
Opposite of the correct reason, so false.D: more reactive nature of the actinoids than the lanthanoids
Reactivity alone is not the main reason for larger number of oxidation states. -
Final answer
Therefore, the correct option is:
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