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D and F Block Elements question

2002 · Shift 0 · Q47
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D and F Block Elements question

2002 · Shift 0 · Q47

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Most common oxidation states of Ce (cerium) are :
  1. A
    +3, +4
  2. B
    +2, +3
  3. C
    +2, +4
  4. D
    +3, +5
View written solutionFree

Correct answer: A

  1. Identify the element and its series

    Cerium, Ce\mathrm{Ce}Ce, is a lanthanoid element.

  2. Write its electronic configuration

    The atomic number of cerium is 585858.

    Its electronic configuration is approximately: Ce:[Xe] 4f15d16s2\mathrm{Ce}: [\mathrm{Xe}]\,4f^1 5d^1 6s^2Ce:[Xe]4f15d16s2

  3. Determine the common oxidation states

    Lanthanoids most commonly show the oxidation state +3+3+3 due to loss of two 6s6s6s electrons and one 5d/4f5d/4f5d/4f electron.

    For cerium, an additional electron can also be lost to give the stable +4+4+4 oxidation state.

    Thus, cerium commonly shows: +3 and +4+3 \text{ and } +4+3 and +4

  4. Check the options

    • A: +3,+4+3, +4+3,+4 ✓ Correct
    • B: +2,+3+2, +3+2,+3 ✗ +2+2+2 is not a common oxidation state of cerium
    • C: +2,+4+2, +4+2,+4 ✗ +2+2+2 is not common
    • D: +3,+5+3, +5+3,+5 ✗ +5+5+5 is not a common oxidation state of cerium
  5. Final answer

    The most common oxidation states of cerium are: +3,+4\boxed{+3, +4}+3,+4​

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