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D and F Block Elements question

2025 · 7 Apr · Shift 1 · Q7
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D and F Block Elements question

2025 · 7 Apr · Shift 1 · Q7

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The first transition series metal ' MMM' has the highest enthalpy of atomisation in its series. One of its aquated ion (Mn+)\left(\mathrm{M}^{\mathrm{n}+}\right)(Mn+) exists in green colour. The nature of the oxide formed by the above Mn+\mathrm{M}^{\mathrm{n}+}Mn+ ion is:
  1. A
    basic
  2. B
    neutral
  3. C
    amphoteric
  4. D
    acidic
View written solutionFree

Correct answer: A

  1. Identify the metal MMM

In the first transition series (3d3d3d-series), the metal with the highest enthalpy of atomisation is chromium.

This is because chromium has strong metallic bonding due to the presence of many unpaired electrons.

So, M=CrM = \mathrm{Cr}M=Cr

  1. Identify the green aquated ion

Chromium forms several ions, and one common green aquated ion is: [Cr(H2O)6]2+[\mathrm{Cr(H_2O)_6}]^{2+}[Cr(H2​O)6​]2+ which corresponds to Cr2+\mathrm{Cr}^{2+}Cr2+

Thus, in the statement, the relevant ion is Mn+=Cr2+\mathrm{M}^{n+} = \mathrm{Cr}^{2+}Mn+=Cr2+

  1. Determine the oxide formed by this ion

The oxide of Cr2+\mathrm{Cr}^{2+}Cr2+ is: CrO\mathrm{CrO}CrO

Here chromium is in the +2 oxidation state.

  1. Nature of CrO\mathrm{CrO}CrO

For transition metals, lower oxidation state oxides are basic, intermediate ones are amphoteric, and higher oxidation state oxides are acidic.

Since CrO\mathrm{CrO}CrO is chromium in the low oxidation state +2+2+2, it is a basic oxide.

  1. Check options
  • A: basic →\rightarrow→ Correct
  • B: neutral →\rightarrow→ Incorrect
  • C: amphoteric →\rightarrow→ Incorrect
  • D: acidic →\rightarrow→ Incorrect

Therefore, the correct answer is: A: basic\boxed{\text{A: basic}}A: basic​

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