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D and F Block Elements question

2025 · 3 Apr · Shift 1 · Q22
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D and F Block Elements question

2025 · 3 Apr · Shift 1 · Q22

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
Consider the following reactions A+NaCl Little  amount +H2SO4→CrO2Cl2+ Side Products CrO2Cl2 (Vapour) +NaOH→ B+NaCl+H2O B+H+→C+H2O\begin{aligned} & \mathrm{A}+\underset{\substack{ \text { Little } \\ \text { amount }}}{\mathrm{NaCl}}+\mathrm{H}_2 \mathrm{SO}_4 \rightarrow \mathrm{CrO}_2 \mathrm{Cl}_2+\text { Side Products } \\ & \mathrm{CrO}_2 \mathrm{Cl}_{2 \text { (Vapour) }}+\mathrm{NaOH} \rightarrow \mathrm{~B}+\mathrm{NaCl}+\mathrm{H}_2 \mathrm{O} \\ & \mathrm{~B}+\mathrm{H}^{+} \rightarrow \mathrm{C}+\mathrm{H}_2 \mathrm{O} \end{aligned}​A+ Little  amount ​NaCl​+H2​SO4​→CrO2​Cl2​+ Side Products CrO2​Cl2 (Vapour) ​+NaOH→ B+NaCl+H2​O B+H+→C+H2​O​ The number of terminal 'OOO ' present in the compound ' C ' is ‾\underline{\hspace{2cm}}​
Numerical answer
View written solutionFree

Correct answer: 6

  1. Identify compound AAA from the first reaction

A compound that gives chromyl chloride, CrO2Cl2\mathrm{CrO_2Cl_2}CrO2​Cl2​, on heating with a little NaCl\mathrm{NaCl}NaCl and concentrated H2SO4\mathrm{H_2SO_4}H2​SO4​ is a chromate/dichromate compound. This is the well-known chromyl chloride test for chromium.

So effectively, chromium in AAA is converted to chromyl chloride: CrO42−/Cr2O72−→H2SO4NaClCrO2Cl2\mathrm{CrO_4^{2-}/Cr_2O_7^{2-} \xrightarrow[H_2SO_4]{NaCl} CrO_2Cl_2}CrO42−​/Cr2​O72−​NaClH2​SO4​​CrO2​Cl2​

  1. Reaction of chromyl chloride with NaOH

Chromyl chloride on hydrolysis/alkaline treatment gives chromate: CrO2Cl2+4NaOH→Na2CrO4+2NaCl+2H2O\mathrm{CrO_2Cl_2 + 4NaOH \rightarrow Na_2CrO_4 + 2NaCl + 2H_2O}CrO2​Cl2​+4NaOH→Na2​CrO4​+2NaCl+2H2​O

Hence, B=Na2CrO4B = \mathrm{Na_2CrO_4}B=Na2​CrO4​

  1. Acidification of chromate

On adding acid, chromate converts to dichromate: 2CrO42−+2H+⇌Cr2O72−+H2O2\mathrm{CrO_4^{2-}} + 2\mathrm{H^+} \rightleftharpoons \mathrm{Cr_2O_7^{2-}} + \mathrm{H_2O}2CrO42−​+2H+⇌Cr2​O72−​+H2​O

Thus, C=Cr2O72−C = \mathrm{Cr_2O_7^{2-}}C=Cr2​O72−​

  1. Count the terminal oxygen atoms in CCC

Structure of dichromate ion, Cr2O72−\mathrm{Cr_2O_7^{2-}}Cr2​O72−​:

  • It contains one bridging oxygen between the two chromium atoms.
  • Total oxygen atoms = 777
  • Therefore, terminal oxygens = 7−1=67 - 1 = 67−1=6

So, the number of terminal oxygen atoms in CCC is: 6\boxed{6}6​

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