JEE MainChemistryD and F Block ElementsNumerical+4 / −1
Consider the following reactions The number of terminal ' ' present in the compound ' C ' is
Numerical answer
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Correct answer: 6
- Identify compound from the first reaction
A compound that gives chromyl chloride, , on heating with a little and concentrated is a chromate/dichromate compound. This is the well-known chromyl chloride test for chromium.
So effectively, chromium in is converted to chromyl chloride:
- Reaction of chromyl chloride with NaOH
Chromyl chloride on hydrolysis/alkaline treatment gives chromate:
Hence,
- Acidification of chromate
On adding acid, chromate converts to dichromate:
Thus,
- Count the terminal oxygen atoms in
Structure of dichromate ion, :
- It contains one bridging oxygen between the two chromium atoms.
- Total oxygen atoms =
- Therefore, terminal oxygens =
So, the number of terminal oxygen atoms in is:
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