Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Coordination Compounds question

2022 · 30 Jun · Shift 1 · Q20
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Coordination Compounds
  5. /2022 · 30 Jun · Shift 1 · Q20

Coordination Compounds question

2022 · 30 Jun · Shift 1 · Q20

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
Spin only magnetic moment (μ\muμ s) of K3[Fe(CN)6]{K_3}[Fe{(CN)_6}]K3​[Fe(CN)6​] is ‾\underline{\hspace{2cm}}​ B.M. (Nearest integer)
Numerical answer
View written solutionFree

Correct answer: 2

  1. Find oxidation state of Fe in K3[Fe(CN)6]K_3[Fe(CN)_6]K3​[Fe(CN)6​]

    Let oxidation state of Fe be xxx.

    In the complex ion [Fe(CN)6]3−[Fe(CN)_6]^{3-}[Fe(CN)6​]3−:

    • Each CN−CN^-CN− ligand has charge −1-1−1
    • Total ligand charge =6(−1)=−6= 6(-1) = -6=6(−1)=−6

    So, x−6=−3x - 6 = -3x−6=−3 x=+3x = +3x=+3

    Hence, iron is Fe3+Fe^{3+}Fe3+.

  2. Write electronic configuration of Fe3+Fe^{3+}Fe3+

    Atomic number of Fe = 26.

    Neutral Fe: [Ar]3d64s2[Ar]3d^6 4s^2[Ar]3d64s2

    For Fe3+Fe^{3+}Fe3+, remove two electrons from 4s4s4s and one from 3d3d3d: Fe3+=[Ar]3d5Fe^{3+} = [Ar]3d^5Fe3+=[Ar]3d5

  3. Nature of ligand CN−CN^-CN−

    CN−CN^-CN− is a strong field ligand, so it causes pairing of electrons in the ddd-orbitals.

    For an octahedral complex with d5d^5d5 configuration and strong field ligands, we get low-spin arrangement: t2g5eg0t_{2g}^5 e_g^0t2g5​eg0​

  4. Count number of unpaired electrons

    In t2g5t_{2g}^5t2g5​:

    • two orbitals are paired
    • one orbital has one unpaired electron

    Therefore, number of unpaired electrons: n=1n = 1n=1

  5. Calculate spin-only magnetic moment

    Formula: μs=n(n+2)  B.M.\mu_s = \sqrt{n(n+2)}\;\text{B.M.}μs​=n(n+2)​B.M.

    Substituting n=1n=1n=1: μs=1(1+2)=3≈1.73  B.M.\mu_s = \sqrt{1(1+2)} = \sqrt{3} \approx 1.73\;\text{B.M.}μs​=1(1+2)​=3​≈1.73B.M.

  6. Nearest integer

    1.73≈21.73 \approx 21.73≈2

Final Answer

Spin-only magnetic moment of K3[Fe(CN)6]K_3[Fe(CN)_6]K3​[Fe(CN)6​] is: 2\boxed{2}2​

PreviousNext

More from Coordination Compounds

  • Correct formula of the compound which gives a white precipitate with BaCl2​ solution, but not with AgNO3​ solution, is :2022 · MCQ
  • The potassium ferrocyanide solution gives a Prussian blue colour, when added to :2021 · MCQ
  • The sum of oxidation states of two silver ions in [Ag(NH3​)2​] [Ag(CN)2​] complex is ​.2021 · Numerical
  • The Crystal Field Stabilization Energy (CFSE) and magnetic moment (spin-only) of an octahedral aqua complex of a metal ion (Mz+) are − 0.8 Δ 0 and 3.87 BM, respectively. Identify (Mz+) :2021 · MCQ
  • The equivalents of ethylene diamine required to replace the neutral ligands from the coordination sphere of the trans-complex of CoCl3​ . 4NH3​ is ​. (Round off to the Nearest Integer).2021 · Numerical
  • [Ti(H2​O)6​]3+ absorbs light of wavelength 498 nm during a d − d transition. The octahedral splitting energy for the above complex is ​× 10 − 19 J. (Round off to the Nearest Integer). h = 6.626 ×…2021 · Numerical
  • Match List - I with List - II : Choose the correct answer from the options given below : Includes table2021 · MCQ
  • On complete reaction of FeCl3​ with oxalic acid in aqueous solution containing KOH, resulted in the formation of product A. The secondary valency of Fe in the product A is ​. (Round off to the Nearest…2021 · Numerical