JEE MainChemistryCoordination CompoundsNumerical+4 / −1
Spin only magnetic moment ( s) of is B.M. (Nearest integer)
Numerical answer
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Correct answer: 2
-
Find oxidation state of Fe in
Let oxidation state of Fe be .
In the complex ion :
- Each ligand has charge
- Total ligand charge
So,
Hence, iron is .
-
Write electronic configuration of
Atomic number of Fe = 26.
Neutral Fe:
For , remove two electrons from and one from :
-
Nature of ligand
is a strong field ligand, so it causes pairing of electrons in the -orbitals.
For an octahedral complex with configuration and strong field ligands, we get low-spin arrangement:
-
Count number of unpaired electrons
In :
- two orbitals are paired
- one orbital has one unpaired electron
Therefore, number of unpaired electrons:
-
Calculate spin-only magnetic moment
Formula:
Substituting :
-
Nearest integer
Final Answer
Spin-only magnetic moment of is:
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