JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The oxidation states of iron atoms in compounds (A), (B) and (C), respectively, are x, y and z. The sum of x, y and z is . (A) (B) (C)
Numerical answer
View written solutionFree
Correct answer: 6
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Find oxidation state in (A):
- The complex ion is because there are ions.
- Each ligand has charge , so cyanides contribute .
- The ligand here is nitrosyl sulphide written as . Its charge is .
- Let oxidation state of Fe be .
Then,
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Find oxidation state in (B):
- The complex ion is .
- Oxygen is each, so oxygens contribute .
- Let oxidation state of Fe be .
Then,
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Find oxidation state in (C):
- Carbon monoxide, , is a neutral ligand.
- The complex is overall neutral.
- Let oxidation state of each Fe be .
Then,
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Calculate the sum:
Therefore, the required sum is:
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Comparison with stored answer:
Stored correct answer =
Our derived answer also = . So they agree.
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