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Coordination Compounds question

2020 · 2 Sep · Shift 1 · Q2
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Coordination Compounds question

2020 · 2 Sep · Shift 1 · Q2

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The oxidation states of iron atoms in compounds (A), (B) and (C), respectively, are x, y and z. The sum of x, y and z is ‾\underline{\hspace{2cm}}​. Na4[Fe(CN)5(NOS)]Na_4[Fe(CN)_5(NOS)]Na4​[Fe(CN)5​(NOS)] (A) Na4[FeO4]Na_4[FeO_4]Na4​[FeO4​] (B) [Fe2(CO)9][Fe_2(CO)_9][Fe2​(CO)9​] (C)
Numerical answer
View written solutionFree

Correct answer: 6

  1. Find oxidation state in (A): Na4[Fe(CN)5(NOS)]Na_4[Fe(CN)_5(NOS)]Na4​[Fe(CN)5​(NOS)]

    • The complex ion is [Fe(CN)5(NOS)]4−[Fe(CN)_5(NOS)]^{4-}[Fe(CN)5​(NOS)]4− because there are 444 Na+Na^+Na+ ions.
    • Each CN−CN^-CN− ligand has charge −1-1−1, so 555 cyanides contribute −5-5−5.
    • The ligand NOSNOSNOS here is nitrosyl sulphide written as NOS−NOS^-NOS−. Its charge is −1-1−1.
    • Let oxidation state of Fe be xxx.

    Then, x+5(−1)+(−1)=−4x + 5(-1) + (-1) = -4x+5(−1)+(−1)=−4 x−6=−4x - 6 = -4x−6=−4 x=+2x = +2x=+2

  2. Find oxidation state in (B): Na4[FeO4]Na_4[FeO_4]Na4​[FeO4​]

    • The complex ion is [FeO4]4−[FeO_4]^{4-}[FeO4​]4−.
    • Oxygen is −2-2−2 each, so 444 oxygens contribute −8-8−8.
    • Let oxidation state of Fe be yyy.

    Then, y+4(−2)=−4y + 4(-2) = -4y+4(−2)=−4 y−8=−4y - 8 = -4y−8=−4 y=+4y = +4y=+4

  3. Find oxidation state in (C): [Fe2(CO)9][Fe_2(CO)_9][Fe2​(CO)9​]

    • Carbon monoxide, COCOCO, is a neutral ligand.
    • The complex is overall neutral.
    • Let oxidation state of each Fe be zzz.

    Then, 2z+9(0)=02z + 9(0) = 02z+9(0)=0 2z=02z = 02z=0 z=0z = 0z=0

  4. Calculate the sum:

    x+y+z=2+4+0=6x + y + z = 2 + 4 + 0 = 6x+y+z=2+4+0=6

Therefore, the required sum is: 6\boxed{6}6​

  1. Comparison with stored answer:

    Stored correct answer = 666

    Our derived answer also = 666. So they agree.

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