- A(II) and (IV)
- B(I) and (II)
- C(I) and (III)
- D(III) and (IV)
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Correct answer: C
- Identify the geometry and possible isomers
The complex ion is which is an octahedral complex of type .
Such complexes show cis and trans isomerism.
The product is which is an octahedral complex of type .
Such complexes have two geometrical isomers:
- fac
- mer
So, we need to see whether substitution of one by from the given reactant leads to one or two possible product geometries.
- Case 1: Reactant is cis-
In the cis isomer, the two ligands are adjacent. After replacement of one by , the product has three ligands total.
Now consider the positions available for the incoming relative to the two already present adjacent ligands:
- If the new occupies the position cis to both existing ligands, then all three ligands lie on one face of the octahedron, giving the fac isomer.
- If the new occupies a position such that one pair becomes trans, then the arrangement becomes mer.
Thus, from the cis reactant, two isomers of are possible.
So, statement (I) is correct.
And therefore statement (IV) is false.
- Case 2: Reactant is trans-
In the trans isomer, the two ligands are opposite to each other. After substitution of one by , there are three ligands total.
Since two bromides are already trans, in the product there must remain a trans pair among the three bromides. That corresponds only to the mer arrangement.
The fac isomer cannot be formed because in fac-, all three identical ligands are mutually cis; there is no trans pair.
Hence, from the trans reactant, only one isomer is produced.
So, statement (III) is correct.
And therefore statement (II) is false.
- Evaluate the statements
- (I) Two isomers are produced if the reactant complex ion is a cis-isomer True
- (II) Two isomers are produced if the reactant complex ion is a trans-isomer False
- (III) Only one isomer is produced if the reactant complex ion is a trans-isomer True
- (IV) Only one isomer is produced if the reactant complex ion is a cis-isomer False
Therefore, the correct combination is:
So the correct option is:
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