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Coordination Compounds question

2018 · Shift 0 · Q13
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Coordination Compounds question

2018 · Shift 0 · Q13

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Consider the following reaction and statements: [Co(NH3)4Br2]+[Co(NH_3)_4Br_2]^+[Co(NH3​)4​Br2​]+ + Br−Br^-Br− →\to→ [Co(NH3)3Br3][Co(NH_3)_3Br_3][Co(NH3​)3​Br3​] + NH3NH_3NH3​ (I) Two isomers are produced if the reactant complex ion is a cis-isomer (II) Two isomers are produced if the reactant complex ion is a trans-isomer (III) Only one isomer is produced if the reactant complex ion is a trans-isomer (IV) Only one isomer is produced if the reactant complex ion is a cis – isomer The correct statements are
  1. A
    (II) and (IV)
  2. B
    (I) and (II)
  3. C
    (I) and (III)
  4. D
    (III) and (IV)
View written solutionFree

Correct answer: C

  1. Identify the geometry and possible isomers

The complex ion is [Co(NH3)4Br2]+[Co(NH_3)_4Br_2]^+[Co(NH3​)4​Br2​]+ which is an octahedral complex of type MA4B2MA_4B_2MA4​B2​.

Such complexes show cis and trans isomerism.

The product is [Co(NH3)3Br3][Co(NH_3)_3Br_3][Co(NH3​)3​Br3​] which is an octahedral complex of type MA3B3MA_3B_3MA3​B3​.

Such complexes have two geometrical isomers:

  • fac
  • mer

So, we need to see whether substitution of one NH3NH_3NH3​ by Br−Br^-Br− from the given reactant leads to one or two possible product geometries.


  1. Case 1: Reactant is cis-[Co(NH3)4Br2]+[Co(NH_3)_4Br_2]^+[Co(NH3​)4​Br2​]+

In the cis isomer, the two BrBrBr ligands are adjacent. After replacement of one NH3NH_3NH3​ by Br−Br^-Br−, the product has three BrBrBr ligands total.

Now consider the positions available for the incoming BrBrBr relative to the two already present adjacent BrBrBr ligands:

  • If the new BrBrBr occupies the position cis to both existing BrBrBr ligands, then all three BrBrBr ligands lie on one face of the octahedron, giving the fac isomer.
  • If the new BrBrBr occupies a position such that one pair becomes trans, then the arrangement becomes mer.

Thus, from the cis reactant, two isomers of [Co(NH3)3Br3][Co(NH_3)_3Br_3][Co(NH3​)3​Br3​] are possible.

So, statement (I) is correct.

And therefore statement (IV) is false.


  1. Case 2: Reactant is trans-[Co(NH3)4Br2]+[Co(NH_3)_4Br_2]^+[Co(NH3​)4​Br2​]+

In the trans isomer, the two BrBrBr ligands are opposite to each other. After substitution of one NH3NH_3NH3​ by Br−Br^-Br−, there are three BrBrBr ligands total.

Since two bromides are already trans, in the product there must remain a trans pair among the three bromides. That corresponds only to the mer arrangement.

The fac isomer cannot be formed because in fac-MA3B3MA_3B_3MA3​B3​, all three identical ligands are mutually cis; there is no trans pair.

Hence, from the trans reactant, only one isomer is produced.

So, statement (III) is correct.

And therefore statement (II) is false.


  1. Evaluate the statements
  • (I) Two isomers are produced if the reactant complex ion is a cis-isomer →\rightarrow→ True
  • (II) Two isomers are produced if the reactant complex ion is a trans-isomer →\rightarrow→ False
  • (III) Only one isomer is produced if the reactant complex ion is a trans-isomer →\rightarrow→ True
  • (IV) Only one isomer is produced if the reactant complex ion is a cis-isomer →\rightarrow→ False

Therefore, the correct combination is: (I) and (III)\boxed{\text{(I) and (III)}}(I) and (III)​

So the correct option is: C\boxed{\text{C}}C​

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