JEE MainChemistryCoordination CompoundsMCQ+4 / −1
The number of geometric isomers that can exist for square planar is (py = pyridine) :
- A3
- B4
- C6
- D2
View written solutionFree
Correct answer: A
- Identify the complex type
The complex is
Pt(II) complexes are typically square planar.
Here, all four ligands are different monodentate ligands:
So this is of the type: for a square planar complex.
- Geometrical isomerism in square planar
In a square planar complex, geometrical isomerism depends on which ligands are trans to each other.
Since there are 4 different ligands, a geometric isomer is determined by choosing one pair of ligands to be trans; the remaining two automatically become trans to each other.
The number of distinct ways to partition 4 different ligands into 2 trans pairs is:
These are:
- and
- and
- and
Thus, there are 3 distinct geometric isomers.
- Check options
- A: 3 ✓
- B: 4 ✗
- C: 6 ✗
- D: 2 ✗
- Final answer
The number of geometric isomers is:
More from Coordination Compounds
- Which of the following compounds is not colored yellow?2015 · MCQ
- The equation which is balanced and represents the correct product(s) is :2014 · MCQ
- The octahedral complex of a metal ion with four monodentate ligands , , and absorb wavelengths in the region of red, green, yellow and blue, respectively. The increasing order of ligand strength of the four…2014 · MCQ
- Which of the following complex species is not expected to exhibit optical isomerism?2013 · MCQ
- Which among the following will be named as dibromidobis (ethylene diamine) chromium(III) bromide?2012 · MCQ
- The magnetic moment (spin only) of is2011 · MCQ
- Which of the following facts about the complex is wrong?2011 · MCQ
- A solution containing 2.675g of . 6 (molar mass = 267.5 g mol–1) is passed through a cation exchanger. The chloride ions obtained in solution were treated with excess of to give 4.78 g of (molar mass = 143.5 g…2010 · MCQ