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Coordination Compounds question

2015 · Shift 0 · Q15
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Coordination Compounds question

2015 · Shift 0 · Q15

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
The number of geometric isomers that can exist for square planar [Pt(Cl)(py)(NH3)(NH2OH)]+[Pt (Cl) (py) (NH_3) (NH_2OH)]^+[Pt(Cl)(py)(NH3​)(NH2​OH)]+ is (py = pyridine) :
  1. A
    3
  2. B
    4
  3. C
    6
  4. D
    2
View written solutionFree

Correct answer: A

  1. Identify the complex type

The complex is [Pt(Cl)(py)(NH3)(NH2OH)]+[\text{Pt}(\text{Cl})(\text{py})(\text{NH}_3)(\text{NH}_2\text{OH})]^+[Pt(Cl)(py)(NH3​)(NH2​OH)]+

Pt(II) complexes are typically square planar.

Here, all four ligands are different monodentate ligands:

  • Cl\text{Cl}Cl
  • py\text{py}py
  • NH3\text{NH}_3NH3​
  • NH2OH\text{NH}_2\text{OH}NH2​OH

So this is of the type: [Mabcd][Mabcd][Mabcd] for a square planar complex.

  1. Geometrical isomerism in square planar [Mabcd][Mabcd][Mabcd]

In a square planar complex, geometrical isomerism depends on which ligands are trans to each other.

Since there are 4 different ligands, a geometric isomer is determined by choosing one pair of ligands to be trans; the remaining two automatically become trans to each other.

The number of distinct ways to partition 4 different ligands into 2 trans pairs is: 12(42)=3\frac{1}{2}\binom{4}{2} = 321​(24​)=3

These are:

  • (Cl trans py)(\text{Cl} \text{ trans py})(Cl trans py) and (NH3 trans NH2OH)(\text{NH}_3 \text{ trans NH}_2\text{OH})(NH3​ trans NH2​OH)
  • (Cl trans NH3)(\text{Cl} \text{ trans NH}_3)(Cl trans NH3​) and (py trans NH2OH)(\text{py} \text{ trans NH}_2\text{OH})(py trans NH2​OH)
  • (Cl trans NH2OH)(\text{Cl} \text{ trans NH}_2\text{OH})(Cl trans NH2​OH) and (py trans NH3)(\text{py} \text{ trans NH}_3)(py trans NH3​)

Thus, there are 3 distinct geometric isomers.

  1. Check options
  • A: 3 ✓
  • B: 4 ✗
  • C: 6 ✗
  • D: 2 ✗
  1. Final answer

The number of geometric isomers is: 3\boxed{3}3​

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