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Coordination Compounds question

2016 · Shift 0 · Q16
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Coordination Compounds question

2016 · Shift 0 · Q16

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
  1. A
    cis[Co(en)2Cl2]Cl[Co(en)_2Cl_2]Cl[Co(en)2​Cl2​]Cl
  2. B
    trans[Co(en)2Cl2]Cl[Co(en)_2Cl_2]Cl[Co(en)2​Cl2​]Cl
  3. C
    [Co(NH3)4Cl2]Cl[Co(NH_3)_4Cl_2]Cl[Co(NH3​)4​Cl2​]Cl
  4. D
    [Co(NH3)3Cl3][Co(NH_3)_3Cl_3][Co(NH3​)3​Cl3​]
View written solutionFree

Correct answer: A

  1. Identify the coordination geometry

All the given cobalt complexes are octahedral 666-coordinate complexes.

  1. Recall the condition for optical isomerism

A coordination compound shows optical isomerism if it is chiral, i.e. it has no plane of symmetry, no center of symmetry, and its mirror image is non-superimposable.

We now check each option.


  1. Option A: cis[Co(en)2Cl2]Cl\text{cis}[Co(en)_2Cl_2]Clcis[Co(en)2​Cl2​]Cl

The complex ion is [Co(en)2Cl2]+[Co(en)_2Cl_2]^+[Co(en)2​Cl2​]+.

  • It is an octahedral complex of type [M(en)2a2][M(en)_2a_2][M(en)2​a2​].
  • Since enenen is a bidentate ligand, it forms chelate rings.
  • In the cis form, the arrangement of the two enenen rings creates a helical, non-superimposable mirror image.
  • Thus the cis form is chiral and shows optical isomerism.

So, Option A shows optical isomerism.


  1. Option B: trans[Co(en)2Cl2]Cl\text{trans}[Co(en)_2Cl_2]Cltrans[Co(en)2​Cl2​]Cl

The complex ion is [Co(en)2Cl2]+[Co(en)_2Cl_2]^+[Co(en)2​Cl2​]+.

  • In the trans form, the two identical Cl−Cl^-Cl− ligands are opposite each other.
  • This arrangement has symmetry elements (in particular, it is not chiral).
  • Therefore it does not show optical isomerism.

So, Option B is not optically active.


  1. Option C: [Co(NH3)4Cl2]Cl[Co(NH_3)_4Cl_2]Cl[Co(NH3​)4​Cl2​]Cl

The complex ion is [Co(NH3)4Cl2]+[Co(NH_3)_4Cl_2]^+[Co(NH3​)4​Cl2​]+, of type [MA4B2][MA_4B_2][MA4​B2​].

  • Such complexes show geometrical isomerism (cis/trans).
  • But because all ligands are monodentate, these forms have symmetry and are not optically active.

So, Option C does not show optical isomerism.


  1. Option D: [Co(NH3)3Cl3][Co(NH_3)_3Cl_3][Co(NH3​)3​Cl3​]

This is of type [MA3B3][MA_3B_3][MA3​B3​].

  • It can show fac/mer geometrical isomerism.
  • However, neither fac nor mer form is optically active in this case.

So, Option D does not show optical isomerism.


  1. Final conclusion

Only cis[Co(en)2Cl2]Cl\text{cis}[Co(en)_2Cl_2]Clcis[Co(en)2​Cl2​]Cl shows optical isomerism.

Therefore, the correct answer is:

A\boxed{A}A​

  1. Comparison with stored correct answer

Stored correct answer: AAA

My derived answer: AAA

They agree.

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