JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
- Acis
- Btrans
- C
- D
View written solutionFree
Correct answer: A
- Identify the coordination geometry
All the given cobalt complexes are octahedral -coordinate complexes.
- Recall the condition for optical isomerism
A coordination compound shows optical isomerism if it is chiral, i.e. it has no plane of symmetry, no center of symmetry, and its mirror image is non-superimposable.
We now check each option.
- Option A:
The complex ion is .
- It is an octahedral complex of type .
- Since is a bidentate ligand, it forms chelate rings.
- In the cis form, the arrangement of the two rings creates a helical, non-superimposable mirror image.
- Thus the cis form is chiral and shows optical isomerism.
So, Option A shows optical isomerism.
- Option B:
The complex ion is .
- In the trans form, the two identical ligands are opposite each other.
- This arrangement has symmetry elements (in particular, it is not chiral).
- Therefore it does not show optical isomerism.
So, Option B is not optically active.
- Option C:
The complex ion is , of type .
- Such complexes show geometrical isomerism (cis/trans).
- But because all ligands are monodentate, these forms have symmetry and are not optically active.
So, Option C does not show optical isomerism.
- Option D:
This is of type .
- It can show fac/mer geometrical isomerism.
- However, neither fac nor mer form is optically active in this case.
So, Option D does not show optical isomerism.
- Final conclusion
Only shows optical isomerism.
Therefore, the correct answer is:
- Comparison with stored correct answer
Stored correct answer:
My derived answer:
They agree.
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