- Ao of > and o of >
- Bo of > and o of <
- Co of < and o of >
- Do of < and o of <
View written solutionFree
Correct answer: C
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We need the trend in octahedral crystal field splitting, , for aqua complexes.
For a given ligand ( here), generally depends on:
- oxidation state of the metal: higher oxidation state larger
- principal quantum number / row of transition metal: typically for comparable ions, so heavier congeners usually give larger splitting.
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Compare and
Both have the same metal and same ligand, only oxidation state differs.
- In , metal is
- In , metal is
Since higher oxidation state increases metal-ligand attraction and shortens bond length, we get
So any option saying is incorrect.
Hence options B and D are eliminated.
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Compare and
These are both aqua complexes, but:
- is a element
- is a element
For similar oxidation state and ligand, metals usually have larger crystal field splitting than metals because their orbitals are more diffuse and overlap better with ligands.
Therefore,
or equivalently,
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Match with the options
We need:
This corresponds to Option C.
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Final answer
This matches the stored correct answer.
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