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Coordination Compounds question

2017 · 9 Apr · Shift 1 · Q8
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Coordination Compounds question

2017 · 9 Apr · Shift 1 · Q8

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
[Co2(CO)8][Co_2(CO)_8][Co2​(CO)8​] displays :
  1. A
    one Co−Co bond, six terminal CO and two bridging CO
  2. B
    one Co−Co bond, four terminal CO and four bridging CO
  3. C
    no Co−Co bond, six terminal CO and two bridging CO
  4. D
    no Co−Co bond, four terminal CO and four bridging CO
View written solutionFree

Correct answer: A

  1. We need the structure of [Co2(CO)8][Co_2(CO)_8][Co2​(CO)8​].

  2. This is a well-known metal carbonyl dimer. Its usual structure contains:

    • one Co−Co\mathrm{Co-Co}Co−Co bond
    • two bridging carbonyls (μ\muμ-CO)
    • six terminal carbonyls
  3. We can also check by electron counting.

    For each Co atom:

    • Cobalt is in group 9, so it contributes 999 electrons.
    • In the bridged dimer form, each Co is bonded to:
      • 333 terminal CO ligands ⇒3×2=6\Rightarrow 3 \times 2 = 6⇒3×2=6 electrons
      • 222 bridging CO ligands, each contributing 111 electron to a given Co in neutral counting ⇒2\Rightarrow 2⇒2 electrons
      • one Co−Co\mathrm{Co-Co}Co−Co bond ⇒1\Rightarrow 1⇒1 electron to each Co

    Total per Co: 9+6+2+1=189 + 6 + 2 + 1 = 189+6+2+1=18

    So the structure satisfies the 181818-electron rule.

  4. Now evaluate the options:

    • A: one Co−Co\mathrm{Co-Co}Co−Co bond, six terminal CO and two bridging CO
      This matches the known structure.

    • B: one Co−Co\mathrm{Co-Co}Co−Co bond, four terminal CO and four bridging CO
      Not the accepted structure for [Co2(CO)8][Co_2(CO)_8][Co2​(CO)8​].

    • C: no Co−Co\mathrm{Co-Co}Co−Co bond, six terminal CO and two bridging CO
      Incorrect, because the dimer has a Co−Co\mathrm{Co-Co}Co−Co bond.

    • D: no Co−Co\mathrm{Co-Co}Co−Co bond, four terminal CO and four bridging CO
      Incorrect.

  5. Therefore, the correct option is: A\boxed{\text{A}}A​

  6. Comparison with stored correct answer:

    • Stored correct answer: A
    • Derived answer: A
    • They agree.
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