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Biomolecules question

2022 · 27 Jul · Shift 1 · Q11
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Biomolecules question

2022 · 27 Jul · Shift 1 · Q11

JEE MainChemistryBiomoleculesMCQ+4 / −1
A sugar 'X' dehydrates very slowly under acidic condition to give furfural which on further reaction with resorcinol gives the coloured product after sometime. Sugar 'X' is
  1. A
    Aldopentose
  2. B
    Aldotetrose
  3. C
    Oxalic acid
  4. D
    Ketotetrose
View written solutionFree

Correct answer: A

  1. Identify the test being described

    The question says:

    • sugar XXX dehydrates very slowly under acidic conditions,
    • forms furfural,
    • which then reacts with resorcinol to give a coloured product.

    This is the basis of Seliwanoff-type differentiation and related furfural/hydroxymethylfurfural tests.

  2. Recall dehydration behavior of sugars in acid

    Under strong acidic conditions:

    • Pentoses dehydrate to give furfural.
    • Hexoses generally give 5-hydroxymethylfurfural.
    • Ketoses dehydrate faster than aldoses.

    Since the product mentioned is specifically furfural, the sugar must be a pentose-type sugar.

  3. Check each option

    Option A: Aldopentose

    • An aldopentose has 5 carbon atoms.
    • On acid dehydration, pentoses form furfural.
    • Being an aldose, the dehydration is relatively slower compared with ketoses.
    • This matches: dehydrates very slowly to give furfural.

    So, A is correct.

    Option B: Aldotetrose

    • A tetrose has 4 carbon atoms.
    • It does not typically give furfural on acid dehydration in the standard carbohydrate tests.
    • Hence this does not match.

    So, B is incorrect.

    Option C: Oxalic acid

    • Oxalic acid is not a sugar.
    • It cannot give furfural in this context.

    So, C is incorrect.

    Option D: Ketotetrose

    • A ketotetrose has 4 carbon atoms.
    • Tetroses do not give the characteristic furfural test described here.
    • Also, ketoses dehydrate faster, but the key issue is that furfural formation here is characteristic of pentoses.

    So, D is incorrect.

  4. Conclusion

    The sugar XXX must be an aldopentose.

Aldopentose\boxed{\text{Aldopentose}}Aldopentose​

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