JEE MainChemistryBiomoleculesMCQ+4 / −1
A sugar 'X' dehydrates very slowly under acidic condition to give furfural which on further reaction with resorcinol gives the coloured product after sometime. Sugar 'X' is
- AAldopentose
- BAldotetrose
- COxalic acid
- DKetotetrose
View written solutionFree
Correct answer: A
-
Identify the test being described
The question says:
- sugar dehydrates very slowly under acidic conditions,
- forms furfural,
- which then reacts with resorcinol to give a coloured product.
This is the basis of Seliwanoff-type differentiation and related furfural/hydroxymethylfurfural tests.
-
Recall dehydration behavior of sugars in acid
Under strong acidic conditions:
- Pentoses dehydrate to give furfural.
- Hexoses generally give 5-hydroxymethylfurfural.
- Ketoses dehydrate faster than aldoses.
Since the product mentioned is specifically furfural, the sugar must be a pentose-type sugar.
-
Check each option
Option A: Aldopentose
- An aldopentose has 5 carbon atoms.
- On acid dehydration, pentoses form furfural.
- Being an aldose, the dehydration is relatively slower compared with ketoses.
- This matches: dehydrates very slowly to give furfural.
So, A is correct.
Option B: Aldotetrose
- A tetrose has 4 carbon atoms.
- It does not typically give furfural on acid dehydration in the standard carbohydrate tests.
- Hence this does not match.
So, B is incorrect.
Option C: Oxalic acid
- Oxalic acid is not a sugar.
- It cannot give furfural in this context.
So, C is incorrect.
Option D: Ketotetrose
- A ketotetrose has 4 carbon atoms.
- Tetroses do not give the characteristic furfural test described here.
- Also, ketoses dehydrate faster, but the key issue is that furfural formation here is characteristic of pentoses.
So, D is incorrect.
-
Conclusion
The sugar must be an aldopentose.
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